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通过对LiFePO4锂离子电池循环寿命实验,发现电池在不同充放电制度下的循环寿命差异很大。研究发现,单体电池充电终止电压应该在3.65 V左右,超过4.0 V会造成电池循环寿命的严重衰减。单体电池放电截止电压应该尽可能高,应大于2.5 V;充电倍率越高,电池循环寿命越低。在电池组的实际使用中,应该综合考虑这些因素,并采取有效的措施以延长电池组的使用寿命。
Abstract:Lithium iron phosphate(LiFePO4) was used as cathode material to study the cyclic life of Li-ion batteries.It was found that the cyclic life of Li-ion batteries was straightly dependent on the charge-discharge modes.The charge cutoff voltage of single cells should be 3.65 V.If it exceeded 4.0 V,the cyclic life of the cells would decay seriously.The discharge cutoff voltage of Li-ion single cells should be higher than 2.5 V.The cyclic performance of Li-ion batteries were destroyed with the increasing of the charge rates.In practical applications,the above factors should be considered,and some measures should be taken to improve the cyclic life of Li-ion batteries.
[1]Tarascon J M,Arma nd M.Issues and challenges facingrechargeable lithium batteries[J].Nature,2001,414(15):359-367.
[2]Xie H M,Wang R S,YING J R,et al.Optimized LiFePO4-polyacene cathode material for lithium-ion batteries[J].AdvMater,2006,18(19):2609-2613.
[3]Kim M G,Cho J.Reversible and high-capacity nano-structured electrode materials for Li-Ion batteries[J].AdvFunct Mater,2009,19(10):1497-1514.
[4]Uno Y,Tsujikawa T,HIRAIT.Electrochemical properties ofhelical carbon nanomaterials formed on LiCoO2 by chemicalvapor deposition[J].J Power Sources,2010,195(1):354-357.
[5]Wang G X,Zhong S,Bradhurst D H,et al.Synthesis andcharacterization of LiNiO2 compounds as cathodes forrechargeable lithium batteries[J].J Power Sources,1998,76(2):141-146.
[6]Chung K Y,Kim J H,Kim K B.Structural changes inLixMn2O4 at 3.7 V induced by voltage excursions below 3.0 V[J].Electrochem Solid-State Lett,2006,9(4):A186-A189.
[7]PadhiA K,Nanjundaswamy K S,Goodenough J B.Phospho-olivines as positive-electrode materials for rechargeablelithium batteries[J].J Electrochem Soc,1997,144(4):1188-1194.
[8]Kang B,Ceder G.Battery materials for ultrafast charging anddischarging[J].Nature,458(12):190-193.
[9]Doherty C M,Caruso R A,Smarsly B M,et al.Colloidalcrystal templating to produce hierarchically porous LiFePO4electrode materials for high power lithium ion batteries[J].Chem Mater,2009,21(13):2895-2903.
[10]吴赟,蒋新华,解晶莹.锂离子电池循环寿命快速衰减的原因[J].电池,2009,39(4):206-207.
基本信息:
中图分类号:TM912.9
引用信息:
[1]闻人红雁.放电制式对锂离子电池循环寿命的影响[J].电池工业,2011,16(06):325-328.