| 1,753 | 2 | 15 |
| 下载次数 | 被引频次 | 阅读次数 |
水系锌离子电池（AZIBs）因具备高安全性、低成本及环境友好等突出优势，在大规模储能领域展现出广阔的应用前景。然而，锌负极在反复充放电过程中面临枝晶不可控生长、析氢反应（HER）、腐蚀与表面钝化等一系列界面问题，严重制约了电池的循环稳定性，阻碍了其产业化进程。界面工程作为应对上述挑战的关键策略，通过精准调控锌负极与电解液之间的界面反应动力学、优化离子传输路径并改善界面电荷分布，为实现锌均匀沉积、抑制副反应提供了有效途径。本文综述了近年来水系锌离子电池负极界面工程的研究进展，重点围绕人工界面层构建、电解液调控及电极结构设计三个维度，剖析了各类界面调控策略的作用机制、技术优势与现存局限性，并对未来的研究方向提出展望。
Abstract：Aqueous zinc-ion batteries(AZIBs) have shown broad application prospects in large-scale energy storage due to their prominent advantages such as high safety, low cost, and environmental friendliness. However, the zinc anode faces a series of interface issues during repeated chargedischarge cycles, including uncontrollable dendrite growth, hydrogen evolution reaction(HER), corrosion, and surface passivation. These problems severely restrict the long-term cycling stability of the batteries, hindering industrialization process. As a key strategy to address the above challenges, interface engineering provides an effective approach to inhibit side reactions by precisely regulating the interfacial reaction kinetics, optimizing ion transport paths, and improving interfacial charge distribution. This paper systematically reviews the recent research progress on anode interface engineering of AZIBs, focusing on three dimensions, artificial interface layer construction, electrolyte regulation, and electrode structure design. It deeply analyzes the action mechanisms, technical advantages, and existing limitations of various interface regulation strategies while providing perspectives on future research.
[1]Obama B. The irreversible momentum of clean energy[J].Science,2017,355(6321):126-129.
[2]Trancik J E. Renewable energy:Back the renewables boom[J].Nature,2014,507(7492):300-302.
[3]Schubert C. Renewable energy:Making fuels for the future[J].Nature,2011,474(7352):531-533.
[4]董悦，郭晓玲，何晓霞，等．我国动力锂离子电池回收利用行业产废情况研究[J]．电池工业，2025,29(5):427-432.
[5]Feng X N,Ren D S,He X M,et al.Mitigating thermal runaway of lithium-ion batteries[J].Joule,2020,4(4):743-770.
[6]王俊峰，赵乾乾，谢光辉，等．储能用锂离子电池安全技术标准分析比较[J]．电池工业，2025,29(4):317-326.
[7]史伟峰，钮兴，陈波，等．海湾地区铅酸蓄电池最新认证规则解读[J]．电池工业，2023,27(2):74-78.
[8]Calborean A,Murariu T,Morari C.Optimized lead-acid grid architectures for automotive lead-acid batteries:An electrochemical analysis[J].Electrochimica Acta,2021,372:137880.
[9]高志虹，滑夏．钠离子电池用石油沥青基硬碳负极的研究进展[J]．电池工业，2025,29(5):418-426.
[10]Zhu Y H,Liang G J,Cui X,et al.Engineering hosts for Zn anodes in aqueous Zn-ion batteries[J]. Energy&Environmental Science,2024,17(2):369-385.
[11]Liu C X,Xie X S,Lu B G,et al.Electrolyte strategies toward better zinc-ion batteries[J]. ACS Energy Letters,2021,6(3):1015-1033.
[12]Li Y,Wang Z H,Cai Y,et al.Designing advanced aqueous zinc-ion batteries:Principles,strategies,and perspectives[J]. Energy&Environmental Materials,2022,5(3):823-851.
[13]邵译莹，周洋，邓超．活性炭涂层改性锌负极与电化学性能研究[J]．电池工业，2022,26(6):271-274.
[14]Hao J N,Li X L,Zhang S L,et al.Designing dendritefree zinc anodes for advanced aqueous zinc batteries[J].Advanced Functional Materials,2020,30(30):2001263.
[15]Song M,Tan H,Chao D L,et al. Recent advances in Zn-ion batteries[J]. Advanced Functional Materials,2018,28(41):1802564.
[16]Wu X Y,Ji X L. Aqueous batteries get energetic[J].Nature Chemistry,2019,11(8):680-681.
[17]Chao D L,Zhou W H,Xie F X,et al. Roadmap for advanced aqueous batteries:From design of materials to applications[J].Science Advances,2020,6(21):eaba4098.
[18]Ding L Y,Wang L,Gao J C,et al.Facile Zn2+desolvation enabled by local coordination engineering for longcycling aqueous zinc-ion batteries[J]. Advanced Functional Materials,2023,33(32):2301648.
[19]Qin R Z,Wang Y T,Yao L,et al.Progress in interface structure and modification of zinc anode for aqueous batteries[J].Nano Energy,2022,98:107333.
[20]Feng Z Y,Feng Y,Fan F F,et al. Functionalization design of zinc anode for advanced aqueous zinc-ion batteries[J].SusMat,2024,4(2):e184.
[21]Yang Q,Li Q,Liu Z X,et al.Dendrites in Zn-based batteries[J].Advanced Materials,2020,32(48):2001854.
[22]Xie W L,Zhu K Y,Yang H M,et al.Advancements in achieving high reversibility of zinc anode for alkaline zincbased batteries[J].Advanced Materials,2024,36(5):2306154.
[23]Li B Y,Ma Y T,Ma J B,et al.Challenges and opportunities facing zinc anodes for aqueous zinc-ion battery[J].Energy Materials and Devices,2024,2(3):9370044.
[24]Rana A,Roy K,Heil J N,et al.Realizing the kinetic origin of hydrogen evolution for aqueous zinc metal batteries[J].Advanced Energy Materials,2024,14(43):2402521.
[25]Rana A,Faisal M A,Nguyen J H,et al.An electroanalytical perspective on the competitive interplay between zinc deposition and hydrogen evolution in aqueous zinc metal batteries[J].Advanced Energy Materials,2026,16:e03630.
[26]Yu X Y,Chen M,Li Z G,et al.Unlocking dynamic solvation chemistry and hydrogen evolution mechanism in aqueous zinc batteries[J]. Journal of the American Chemical Society,2024,146(25):17103-17113.
[27]Duan A,Luo S,Sun W.Insight into the development of electrolytes for aqueous zinc metal batteries from alkaline to neutral[J].Chinese Chemical Letters,2024,35(2):108337.
[28]Bayaguud A,Fu Y P,Zhu C B.Interfacial parasitic reactions of zinc anodes in zinc ion batteries:Underestimated corrosion and hydrogen evolution reactions and their suppression strategies[J]. Journal of Energy Chemistry,2022,64:246-262.
[29]Nie C H,Wang G L,Wang D D,et al.Recent progress on Zn anodes for advanced aqueous zinc-ion batteries[J].Advanced Energy Materials,2023,13(28):2300606.
[30]Zhou J H,Xie M,Wu F,et al.Ultrathin surface coating of nitrogen-doped graphene enables stable zinc anodes for aqueous zinc-ion batteries[J]. Advanced Materials,2021,33(33):2101649.
[31]Choi C,Park J B,Park J H,et al.Simultaneous manipulation of electron/Zn2+ion flux and desolvation effect enabled by in-situ built ultra-thin oxide-based artificial interphase for controlled deposition of zinc metal anodes[J].Chemical Engineering Journal,2023,456:141015.
[32]Ma C H,Yang K H,Zhao S B,et al. Recyclable and ultrafast fabrication of zinc oxide interface layer enabling highly reversible dendrite-free Zn anode[J]. ACS Energy Letters,2023,8(2):1201-1208.
[33]Chen M,Guo X J,Jiang X,et al. Multi-group polymer coating on Zn anode for high overall conversion efficiency photorechargeable zinc-ion batteries[J]. Angewandte Chemie International Edition,2024,63(39):e202410011.
[34]Zhang Y, Zhang Y X, Deng J, et al. In-situ electrochemically-bonded self-adapting polymeric interface for durable aqueous zinc ion batteries[J].Advanced Functional Materials,2024,34(6):2310995.
[35]Duan J W,Dong J M,Cao R R,et al.Regulated Zn plating and stripping by a multifunctional polymer-alloy interphase layer for stable Zn metal anode[J].Advanced Science,2023,10(29):2303343.
[36]Chen W J,Tan Y,Guo C Y,et al. Biomass-derived polymer as a flexible“zincophilic-hydrophobic” solid electrolyte interphase layer to enable practical Zn metal anodes[J]. Journal of Colloid and Interface Science,2024,669:104-116.
[37]Su W X,Li Z L,Qin W M,et al.Porous organic cage with 3D interpenetrated electronegative channels as artificial SEI for highly reversible zinc anode[J].Advanced Functional Materials,2026,36(16):e20442.
[38]Meng J X,Zhang G Z,Pang L,et al.Zinc-bromine batteries revisited:Unlocking liquid-phase redox chemistry for next-generation energy storage[J].Energy and Environmental Science,2025,18(20):9031-9053.
[39]Chen A S,Zhao C Y,Gao J Z,et al. Multifunctional SEI-like structure coating stabilizing Zn anodes at a large current and capacity[J].Energy&Environmental Science,2023,16(1):275-284.
[40]Cui M W,Yu L D,Hu J,et al. Tailored polymerinorganic bilayer SEI with proton holder feature for aqueous Zn metal batteries[J].Angewandte Chemie International Edition,2025,64(14):e202423531.
[41]Li D Z,Li C L,Liu W J,et al.Constructing a multifunctional SEI layer enhancing kinetics and stabilizing zinc metal anode[J].Advanced Functional Materials,2025,35(6):2415107.
[42]Hu Z Q,Zhang F L,Zhao Y,et al.A self-regulated electrostatic shielding layer toward dendrite-free Zn batteries[J].Advanced Materials,2022,34(37):2203104.
[43]Li T C,Lim Y,Li X L,et al.A universal additive strategy to reshape electrolyte solvation structure toward reversible Zn storage[J]. Advanced Energy Materials,2022,12(15):2103231.
[44]Zhang S J,Hao J N,Luo D,et al.Dual-function electrolyte additive for highly reversible Zn anode[J].Advanced Energy Materials,2021,11(37):2102010.
[45]Liu C J,Xu D M,Liu K H,et al.Ultra-stable aqueous zinc-metal batteries achieved via bio-inspired buffer additive engineering[J].Small,2025,21(51):e11095.
[46]Wang W X,Huang G,Wang Y Z,et al. Organic acid etching strategy for dendrite suppression in aqueous zincion batteries[J].Advanced Energy Materials,2022,12(6):2102797.
[47]Zhou J H,Xie M,Wu F,et al.Encapsulation of metallic Zn in a hybrid MXene/graphene aerogel as a stable Zn anode for foldable Zn-ion batteries[J].Advanced Materials,2022,34:2106897.
[48]Xue P,Guo C,Li L,et al.A MOF-derivative decorated hierarchical porous host enabling ultrahigh rates and superior long-term cycling of dendrite-free Zn metal anodes(adv. Mater. 14/2022)[J]. Advanced Materials,2022,34(14):2270109.
[49]Zhao Y X,Guo S,Chen M J,et al.Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries[J].Nature Communications,2023,14:7080.
[50]Liu M Q,Yang K,Xie Q M,et al.operando evolution of a hybrid metallic alloy interphase for reversible aqueous zinc batteries[J].Angewandte Chemie International Edition,2025,64(5):e202416047.
[51]Li Q,Fang C,Yan C Z. Interfacial alloying-induced optimization of Zn2+diffusion and atomic migration for stable aqueous Zn batteries[J]. Advanced Functional Materials,2025,35(47):2509192.
基本信息:
DOI：10.19996/j.cnki.ChinBatlnd.2026.04.013
中图分类号:TM912
引用信息:
[1]詹念念.水系锌离子电池负极界面工程研究进展[J].电池工业,2026,30(04):512-524.DOI:10.19996/j.cnki.ChinBatlnd.2026.04.013.
基金信息:
河南省自然科学基金（242300420530）
2026-03-12
2026-03-12
2026-03-12