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2023 01 v.27 37-42
废旧磷酸铁锂电池正极材料回收工艺与技术的研究进展
基金项目(Foundation):
邮箱(Email):
DOI: 10.19996/j.cnki.ChinBatlnd.2023.01.008
中文作者单位:

兰州理工大学石油化工学院;

摘要(Abstract):

锂电池具有储能高、寿命长和绿色环保等优点,在各个领域得到了广泛的应用。然而,近些年随着磷酸铁锂电池的大规模使用,大量的废旧磷酸铁锂电池即将到达使用寿命的终点,怎样处置这些废旧电池,这已经是影响锂电池行业发展前景的重要问题之一。本文将对目前废旧磷酸铁锂的回收工艺与技术进行总结概括,对固相法、液相法、固相-液相结合法、氧压浸出法和超临界萃取法的工艺流程与效果的优缺点进行阐述,并对废旧磷酸铁锂电池的回收技术的发展方向进行了展望。

关键词(KeyWords): 磷酸铁锂;锂电池;回收;液相法;固相法
参考文献 [1] ANN L,SONIA K.Global lithium-ion battery capacity to rise five-fold by 2030[EB/OL].woodmac.com,2022.
[2] WANG Q,MAO B,STOLIAROV S I,et al.A review of lithium-ion battery failure mechanisms and fire prevention strategies[J].Progress in Energy and Combustion Science,2019(72):95-131.
[3] 王莉,何向明,高剑.锂离子电池正极材料生产技术的发展[J].储能科学与技术,2018,6(1):888-896.
[4] PADHI A K,NANJUNDASWAMY K S,GOODENOUGH J B.Phospho-olivines as positive-electrode materials for rechargeable lithium batteries[J].Journal of the Electrochemical Society,1997,144(4):1188-1194.
[5] YAMADA A,CHUNG S C,HINOKUMA K.Optimized LiFePO4 for lithium battery cathodes[J].Journal of the Electrochemical Society,2001,148(3):A224.
[6] BURBA C M,FRECH R.Local structure in the Li-ion battery cathode material Lix(MnyFe1-y)PO4 for 0[7] BI H,ZHU H,ZU L,et al.Environment-friendly technology for recovering cathode materials from spent lithium iron phosphate batteries[J].Waste Management & Research:The Journal for a Sustainable Circular Economy,2016(51):204-213.
[8] 樊亚平,晏莉琴,简德超,等.锂离子电池失效中析锂现象的原位检测方法综述[J].储能科学与技术,2019,8(6):1040-1049.
[9] 王其钰,王朔,张杰男,等.锂离子电池失效分析概述[J].储能科学与技术,2017,6(5):1008-1025.
[10] LAIN M J.Recycling of lithium ion cells and batteries[J].Journal of Power Sources,2001,97(1):736-7381.
[11] PAULINO J F,BUSNARDO N G,AFONSO J C.Recovery of valuable elements from spent Li-batteries[J].Journal of Hazardous Materials,2008(150):843-849.
[12] LI L,GE J,WU F,et al.Recovery of cobalt and lithium from spent lithium-ion batteries using organic citric acid as leaching[J].Journal of Hazardous Materials,2010,176(1-3):288-293.
[13] 南俊民,韩东梅,崔明,等.溶剂萃取法从废旧锂离子电池中回收有价金属[J].电池,2004,34(4):309-311.
[14] 昝振峰.废旧LiCoO2锂离子电池回收及再利用研究[D].哈尔滨:哈尔滨工业大学,2013.
[15] 王洪彩.含钴废旧锂离子电池回收技术及中试工艺研究[D].哈尔滨:哈尔滨工业大学,2013.
[16] 谢蕊颖,刘雷鹏,吕生华,等.高储能PVDF基纳米复合材料研究进展[J].绝缘材料.2022,55(3):1-8.
[17] 赵翔宇.废旧磷酸铁锂电池回收处理的研究[D].北京:北京化工大学,2017.
[18] 周旭,贺文智,李光明,等.废旧电池电极材料资源化分离研究[C].废旧机电产品资源化利用处理技术与新设备开发交流研讨会,2009.
[19] 王英东.废旧磷酸铁锂电池正极材料的资源化工艺研究[D].上海:上海第二工业大学,2019.
[20] 刘红晶,焦阳,李冬,等.PVDF膜在碱液下的性能衰减[J].沈阳工业大学学报,2017,39(2):147-152.
[21] 郑茹娟.废旧磷酸盐类及混合锂离子电池回收再利用研究[D].哈尔滨:哈尔滨工业大学,2017.
[22] REIMERS J N,DAHN J R.Electrochemical and in situ X-Ray diffraction studies of lithium intercalation in LixCoO2[J].Journal of the Electrochemical Society,1992,13(8):2091-2097.
[23] 刘云建,胡启阳,李新海.从不合格锂离子蓄电池中直接回收钴酸锂[J].电源技术,2006,130(4):308-310.
[24] LIANG C,XIN C T,YANG Z,et al.Process for the recovery of cobalt oxalate from spent lithium-ion batteries[J].Hydrometallurgy,2011,108(1-2):80-86.
[25] MICHAEL S.Process for recycling negative-electrode materials from spent lithium batteries:US,6511639B[P].2003-01-28.
[26] 卞都成,刘树林,孙永辉,等.废旧LiFePO4正极材料的循环利用及电化学性能[J].硅酸盐学报,2015,43(11):1511-1516
[27] LEE C K,RHEE K I.Preparation of LiCoO2 from spent lithium-ion batteries[J].Journal of Power Sources,2008,109(1):17-21
[28] HAI J B,HUE B Z,LEI Z,et al.Low-temperature thermal pretreatment process for recycling inner core of spent lithium iron phosphate batteries[J].Waste Management & Research,2021,39(1):146-155.
[29] ZHANG W M,HU J S,GUO Y G,et al.Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries[J].Advanced Materials,2008,20(6):1160-1165.
[30] 潘英俊.以磷酸铁锂为正极材料的废旧锂离子电池回收及再利用[D].哈尔滨:哈尔滨工业大学,2012.
[31] 赵红伟,施志聪.废旧磷酸铁锂电池正极材料回收技术进展[J].电池工业,2021,25(5):271-282.
[32] SONG X,HU T,LIANG C,et al.Direct regeneration of cathode materials from spent lithium iron phosphate batteries using a solid phase sintering method[J].RSC Advances,2017(7):4783-4790.
[33] 梁立勃,杨生龙,罗茂枭,等.高温固相法再生废旧磷酸铁锂电池正极材料[J].矿冶工程,2021,41(3):120-128.
[34] 李淑珍.废旧锂电池正极材料原位修复及有价金属电化学分离研究[D].陕西:陕西科技大学,2021.
[35] 刘佩文.废旧磷酸铁锂正极材料的回收与再生研究[D].昆明:昆明理工大学,2021.
[36] 许奎,宋磊,徐婷,等.废旧磷酸铁锂的高效回收再利用[J].电池,2021,51(1):102-106.
[37] 王光旭,李佳,许振明.废旧锂离子电池中有价金属回收工艺的研究进展[J].材料导报,2015,29(4):113-123.
[38] 杜远超,华政,梁风,等.液相法合成磷酸铁锂正极材料[J].化学进展,2017,29(1):137-148.
[39] 张曾.废旧磷酸铁锂电池的综合回收与再生[D].长沙:长沙理工大学,2019.
[40] 王宇.磷酸铁锂电池正极材料中锂、铁的回收工艺条件研究[D].合肥:合肥工业大学,2018.
[41] 许开化,王文杰,李琴香,等.一种废旧锂离子电池中回收锂的方法[P].中国,202011169786.1.
[42] 万青珂.废磷酸铁锂正极粉磷酸法制备磷酸铁工艺研究[D].北京:中国科学院大学,2020.
[43] 白苗苗.硫化镍精矿直接加压浸出的实验研究[D].西安:西安建筑科技大学,2016.
[44] XUE N N,ZHANG Y M,LIU T,et al.Study of the dissolution behavior of muscovite in stone coal by oxygen pressure acid leaching[J].Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science,2016,47(1):694-701.
[45] 伍德佑.废旧磷酸铁锂中锂的回收与铁、磷的综合利用研究[D].广州:广东工业大学,2021.
[46] 许斌.废旧磷酸铁锂正极材料回收再生研究[D].昆明:昆明理工大学,2019.
[47] GROS Q,DUVAL J,WEST C.Eric reseller.On-line supercritical fluid extraction-supercritical fluid chromatography (SFE-SFC) at a glance:A coupling story[J].Trends in Analytical Chemistry,2021(144):116433.
[48]DING X,LIU Q,HOU X P,et al.Supercritical fluid extraction of metal chelate:A Review[J].Critical Reviews in Analytical Chemistry,2016,47(2):99-118.
[49] 李立平,李煜乾,卢超,等.废旧磷酸铁锂正极材料的回收再生方法[P].中国,202010207007.6.
[50] 刘兰胜.磷酸铁锂电池应用现状及发展趋势[J].电池工业,2021,25(5):263-265.
[51] LIU L,ZHANG D C,XU X J,et al.Challenges and development of composite solid electrolytes for all-solid-state lithium batteries[J].Chemical Research in Chinese Universities,2021(37):210-231.
[52] PALLE P M M,JUNG D Y,LEE H,et al.Effect of technological developments for smartphone lithium battery on metal derived resource depletion and toxicity potentials[J].Resources Conservation and Recycling,2020(158):104797.

基本信息:

DOI:10.19996/j.cnki.ChinBatlnd.2023.01.008

中图分类号:X705

引用信息:

[1]李万里,欧玉静.废旧磷酸铁锂电池正极材料回收工艺与技术的研究进展[J].电池工业,2023,27(01):37-42.DOI:10.19996/j.cnki.ChinBatlnd.2023.01.008.

基金信息:

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