| 431 | 8 | 97 |
| 下载次数 | 被引频次 | 阅读次数 |
金属锡比目前广泛使用的碳具有高得多的理论嵌锂比容量,很有希望成为锂离子电池新一代负极材料。综述了近年来锂离子电池锡基负极材料的研究进展,介绍了可作为锂离子电池负极的几种锡基材料的制备方法及性能,并讨论了它们的优缺点。
Abstract:The theoretic specific lithium-insertion capacity of tin is far higher than that of graphite,which is the current anode material for lithium ion batteries.Tin and its alloy are believed to be next anode materials.Progress on the research and development of tin-based anode materials for Li-ion batteries were reviewed in this article.The preparation methods and the performance of different tin-based materials were introduced,and their advantages and disadvantages were discussed too.
[1]郭炳盤,徐徽,王先友,等.锂离子电池[M].长沙:中南大学出版社,2002.145.
[2]M abuchiA,Tokum itsu K,Fujim oto H,eta1.Charge-dis-charge characteristics of the m esocarbon m icrobeads heat-treated at different tem peratures[J].J Electrochem Soc,1996,142(4):1041-1046.
[3]Coutney I,M cKinnon W R,eta1.On the aggregation oftin in SnO com posite glasses caused by the reversible reaction with lithium[J].J Electrochem Soc,1999,146:59-68.
[4]朱承飞,程新群.锂离子电池用金属锡电极的初步研究[J].电池,2002,32(1.):11.
[5]Inaba M,Uno T.Irreversible capacity ofelectrodeposited Sn thin film anode[J].J PowerSources,2005,146:473-477.
[6]Idota Y,Kubate T,M atsufujiA,etal.Tin-based am orphous oxide:a high-capacity lithium-ion storage m aterial[J].Science,1997,276:1395-1397.
[7]Nam S C,Paik C H,Cho B W,etal.Electro-chem ical characterization of various tin-based oxides as negative electrodes for rechargeable lithium batteries[J].J Power source,1999,84:24-31.
[8]Kim H J,Jeong T J.Tin-based oxide as anode m aterials forlithium secondary batteries[J].JElectrochem Soc,2003,150(1.1):A1544-A1547.
[9]Yang J,Takeda Y,Im anishiN,etal.M orphology m odifica-tion and irreversibility com pensation for SnO anodes[J].J Power Source,2001,97-98:216-218.
[10]Subram anian V,Gnanasekar K I.Nanocrystalline SnO2and In-doped SnO2as anode m aterials forlithium batteries[J].Solid State Ionics,2004,175:81-184.
[11]M orim oto H,NakaiM.M echanochem icalsynthesis and anode properties ofSnO-Based am orphous m aterials[J].J Elec-trochem Soc,1999,146(1.1):3970-3973.
[12]Lee J Y,Xiao Y W,Liu Z L,etal.Am orphous Sn2B2O5,Sn2P2O7and Sn2BPO6anodes for lithium ion batteries[J].Solid State Ionics,2000,133:25-35.
[13]LiY,Tu J P.M echanochem icalsynthesis and electrochem-ical properties of nanosized SnS as an anode m aterial for lithium ion batteries[J].M aterials Science and Engineering B,2006,128:75-79.
[14]Fernandz F J,M adrigal.On the structure and electrochem ical reactions with lithium oftin(Ⅱ)phosphate chloride[J].JElectrochem Soc,2000,147(5):1663-1667.
[15]王忠,田文怀,李星国.Sn-Sb合金的氢电弧等离子体法制备及其电化学性能[J].物理化学学报,2006,22(6):752-755.
[16]BEATTIE S D,DAH N J R.Single bath,pulsed electrode-position of copper-tin alloy negative electrodes for lithi-um-ion batteries[J].J Electrochem ical Society,2003,150(7):A894-A898.
[17]Cheng X Q,Shi P F.Electroless Cu-plated Ni3Sn4alloy used as anode m aterialfor lithium ion battery[J].Journalof Alloys and Com pounds,2005,391:241-244.
[18]郑妙生,宋怀河,章颂云,等.Sn/C复合材料的制备及其电化学性能[J].电源技术,2004,28(6):334-337.
[19]Fang L,ChowdariB V R,eta1.Sn-Ca am orphous alloy as anode for lithium ion battery[J].J Power Sources,2001,97-98:181-184.
基本信息:
中图分类号:TM912
引用信息:
[1]田琴,胡社军,李伟善,等.锂离子电池锡基负极材料研究现状[J].电池工业,2007,No.72(06):429-432.
基金信息:
广东省自然科学基金(05200534);; 广州市科技攻关项目(2006Z3-D2031)
2007-12-25
2007-12-25