2006 04 277-281
锂离子电池负极材料的研究进展
基金项目(Foundation):
国家自然科学基金资助项目(50371103)
邮箱(Email):
DOI:
中文作者单位:
中南大学材料科学与工程学院,中南大学材料科学与工程学院,中南大学材料科学与工程学院,中南大学材料科学与工程学院 湖南长沙410083,湖南长沙410083,湖南长沙410083,湖南长沙410083
摘要(Abstract):
锂离子电池的石墨负极材料已商品化,但还存在一些难以克服的弱点。寻找性能更为优良的非碳负极材料仍然是锂离子电池研究的重要课题。综述了在锂离子电池中已实际使用的碳素类负极材料的特点和研究进展情况;介绍了正在探索中的锂离子电池非碳负极材料的研究现状。
关键词(KeyWords):
锂离子电池;;负极材料;;非碳负极材料;;研究进展
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参考文献
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[3]Nam S C,PaiK C H,Cho B W,etal.Electroc-hem icalchar-acterization of various tin-based oxides as negative elec-trodes for rechargeable lithium batteries[J].J PowerSources,1999,84:24-31.
[4]M ao Ou,Dunlap R A,Dahn J R.M echanically alloyed Sn-Fe(C-)powders as anode m aterials for Li-ion batteries I.The Sn2FeC-system[J].J Electrochem Soc,1999,146:405-413.
[5]M ao Ou,Dahn J R.M echanically alloyed Sn-Fe(-C)powders as anode m aterials forLi-ion batteries II.The Sn-Fe system J[].J Electrochem Soc,1999,146:414-422.
[6]M ao Ou,Dahn J R.M echanically alloyed Sn-Fe(-C)powders as anode m aterials for Li-ion batteries III.Sn2Fe:SnFe3C active/inactive com positesJ[].J Electrochem Soc,1999,146:423-427.
[7]Kepler K D,Vaughey J T,Thackeray M M.Copper-tin an-odes for rechargeable lithium batteries:an exam ple of them atrix effectin an interm etallic system[J].J PowerSources,1999,81-82:383-387.
[8]Larcher D,Beaulieu L Y.In-situ X-ray study ofthe elec-trochem ical reaction of Li withη’-Cu6Sn5[J].J Elec-trochem Soc,2000,147:1658-1662.
[9]Basebhard J O,W achtler M.Kinetics of Li insertion intopolycrystal-line and steady state techniques[J].J PowerSources,1999,81-82:268-272.
[10]Yang J,Takeda Y.Ultrafine Sn and SnSb0.14powders forlithium storage m atrices in lithium-ion batteriesJ[].JElectrochem Soc,1999,146:4009-4013.
[11]LiH,LiJ Z.The studies on nanosized m aterials for lithiumion batteriesJ[].Electrochem istry,2000,6:131-145.
[12]Ehrilich G M,Durand C.M etallic negative electrode m ate-rials for rechargeable nonaqueous batteriesJ[].J Elec-trochem Soc,2000,147:886-891.
[13]Fang L,ChowdariB V R.Sn-Ca am orphous alloy as anodeforlithium ion batteryJ[].J PowerSources,2001,97-98∶181-184.
[14]H irokiS,H itohiko H,Takao.Synthesis and anode behaviorof lithium storage interm atellic com pounds with variouscrystallinitiesJ[].J Power Sources,1999,81-82:229-232.
[15]H ansu K,Junghee C,H un-Joon S,et al.The insertionm echanism oflithium into M g2Sianode m aterialfor Li-ionbatteries[J].J Electrochem Soc,1999,146(12):4401-4405.
[16]H ansu K,Byungwoo P,H un-Joon S,etal.Electrochem icalcharacteristics of M gN-i alloys as anode m aterials for sec-ondary LibatteriesJ[].J PowerSources,2000,90(1):59-63.
[17]Cao G S,Zhao X B,LiT,etal.Zn4Sb3(C-7)powders as apotential anode m aterial for lithium i-on batteriesJ[].JPower Sources,2001,94(1):102-107.
[18]H uang S M,Lee H Y,Jang S,etal.Lithium insertion in SiAgpowders produced buy m echanical alloyingJ[].Electro-chem icaland SolidS-tate Letters,2001,4(7):92-96.
[19]Zhang L T,Zhao X B,Jiang X B,etal.Study on the inser-tion behaviors of lithium-ions into CoFe3Sb12 based elec-trodesJ[].J Power Sources,2001,94(1)∶92-96.
[20]H am on Y,Brousse T,Jousse F,etal.Alum inum negativeelectrode in Lithium ion batteriesJ[].J Power Sources,2001,97-98:185-187.
[21]M achillS,RahnerD.Studies ofAl-Al3Nieutectic m ixturesas insertion anodes in rechargeable lithium batteriesJ[].JPower Sources,1997,68:506-509.
[22]M achillS,RahnerD.In situ electrochem icalcharacterizationof lithium a-lloying m aterials for rechargeable anodes inlithium batteriesJ[].JPowerSources,1995,54:428-432.
基本信息:
DOI:
中图分类号:TM912
引用信息:
[1]颜剑,苏玉长,苏继桃等.锂离子电池负极材料的研究进展[J].电池工业,2006(04):277-281.
基金信息:
国家自然科学基金资助项目(50371103)
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