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电解液作为锂离子电池重要组成部分,对电池性能起着非常关键的作用,电解液功能组分的加入是有效改善电解液性能的重要手段。负极成膜添加剂是锂离子电池电解液中不可或缺的功能组分。从成膜反应机理和理论计算方面介绍了近几年来负极成膜添加剂的研究进展,提出了存在的问题和可能的发展趋势。
Abstract：As one of the main parts of Li-ion battery,electrolyte plays a key role in the improvement of battery performance.Utilization of additives is an important way to improve the electrolyte performance.Anode film forming additive is one of the necessary functional composition in electrolyte for lithium ion battery.The recent progress on research and development of negative film-forming additives from the principles or mechanisms of film formation and quantum calculation was reviewed in this paper.The problem and the possible trend in this area were proposed.
[1]倪江锋,周恒辉,陈继涛,等.锂离子电池中固体电解质界面膜(SEI)研究进展[J].化学进展,2004,16(3):
[2]MatsumuraY,Wang S,Mondori J.Mechanism leading to irre-versible capacity loss in Li-ion rechargeable batteries[J].JElectrochem Soc,1995,142(9):2914-2918.
[3]Yamaguchi Sinsitu.Electrochemicai AFM observations of SEIfilm formation on graphite anode[J].Tanso(Japanese),1999,186:39-44.
[4]庄全超,武山.锂离子电池有机电解液成膜添加加剂研究进展[J].化学通报,2003,(11):744-745.
[5]Smori,Hasahima,Hsuzukietal.Chemical properties of variousorganical electrolytes for lithium rechargeable batteries[J].JPower Sources,1997,68:59-64.
[6]Ein-Eli Y,Thomas S R,Koch V R.The role of SO2 as an ad-ditive to organic Li-ion battery electrolytes[J].J ElectrochemSoc,1997,144(4):1159-1165.
[7]Ein-Eli Y.Dithiocarbonic anhydride(CS2)-a new additive inLi-ion battery electrolytes[J].J Electroanalytical Chemistry,2002,531:95-99.
[8]Xu Mengqing,Zuo Xiaoxi,Li Weishan,et al.Effect of butylsultone on the Li-ion battery performance and interface ofgraphite electrode[J].Acta Physico-Chimical Sinica,2006,22(3):335-340.
[9]Zuo Xiaoxi,Xu Mengqing,Li Weishan.Electrochemical re-duction of 1,3-propane sultone on graphite electrode and itsapplication in Li-ion battery.[J].Electrochemical and Solid-State Letters,2006,9(4):A196-A199.
[10]Wrondnigg G H,Wrodnigg T M,Besenhard J O,et al.Propy-lene sulfite as film-forming electrolyte additive in lithiumion batteries[J].Electrochem Comm,1999,1(3-4):148-150.
[11]Aurbach D,Gamolsky K,Markovsky B,et al.On the use ofvinylene carbonate(VC)as an additive to electrolyte solu-tions for Li-ion batteries[J].Electrochim Acta,2002,47(9):1423-1439.
[12]Chen G,Zhuang G,Richardson T,et al.Anodic polymeriza-tion of vinyl ethylene carbonate in Li-ion battery electrolyte[J].Electrochem Solid-State Letters,2005,8(7):A344-A347.
[13]Hu Y,Kong W,Li H,et al.Experimental and theoreticalstudies on reduction mechanism of vinyl ethylene carbonateon graphite anode for lithium ion batteries[J].Electrochem-istry Communications,2004,6:126-131.
[14]Aurbach D,Ein-Eli Y,Markovsky B,et al.The dependenceof the performance of Li-C intercalation anodes for Li-ionsecondary batteries on the electrolyte solution composition[J].Electrochim Acta,1994,39:2559.
[15]Xu K,Zhang S,Jow TR,et al.LiBOB as salt for lithium-ionbatteries:a possible solution for high temperature operation[J].Electrochemical and Solid-State Letters,2002,5(1):A26-A29.
[16]左晓希.锂离子电池电解质溶液功能组分的作用机理及其应用[D].华南理工大学博士学位论文,2006.
[17]黄文煌,严玉顺,万春荣,等.电解液添加剂对锂离子蓄电池循环性能的影响[J].电源技术,2001,25(2):91-93.
[18]Gerhard H,Wrodnigg,Jurgen O.Besenhard,et al.Cyclic anda cyclic sulfites:new solvents and electrolyte additives forlithium-ion batteries with graphitic anodes[J].J PowerSources,2001,97-98:592-594.
基本信息:
中图分类号:TM912
引用信息:
[1]蔡宗平,许梦清,李伟善,等.锂离子电池电解液负极成膜添加剂研究进展[J].电池工业,2008,No.73(01):68-71.
基金信息:
广东省攻关计划(编号2006A10704003);; 广州市科技攻关计划(编号2006Z3-D2031)
2008-02-25
2008-02-25