2021 05 v.25 247-252
锂离子电池硅基负极材料的研发进展
基金项目(Foundation):
邮箱(Email):
DOI:
中文作者单位:
福建南平南孚电池有限公司研究开发部;
摘要(Abstract):
聚焦几类锂离子电池硅基负极材料的研发进展,主要是硅/石墨、硅/碳纳米管、硅/碳纳米线、硅/石墨烯、三维多孔硅复合材料的储锂性能及机理;探讨锂离子电池硅基负极材料目前存在的首效低和安全性不足等问题及掺杂和材料复合等解决途径;展望发展高性能、低成本新型硅基负极材料的研发方向。
关键词(KeyWords):
锂离子电池;负极材料;硅基负极;碳
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参考文献
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[32]LI H,HUANG X J,CHEN L Q,et al.A High Capacity Nano-Si Composite Anode Material for Lithium Rechargeable Batteries[J].Electrochemical and Solid State Letters,1999,2(11):547-549.
[33]YOSHIO M,WANG H Y,FUKUDA K,et al.Carboncoated Si as a Lithium-ion Battery Anode Material[J].Journal of the Electrochemical Society,2002,149(12):A1598-A1603.
[34]QU J,LI H Q,HENRY J J,et al.Self-aligned Cu-Si Coreshell Nanowire Array as a High-performance Anode for Li-ion Batteries[J].Journal of Power Sources,2012,198:312-317.
[35]FU K,YILDIZ O,BHANUSHALI H,et al.Aligned Carbon Nanotube-silicon Sheets:a Novel Nano-architecture for Flexible Lithium ion Battery Electrodes[J].Advanced Materials,2013,25(36):5109-5114.
[2] ETACHERI V,MAROM R,ELAZARI R,et al.Challenges in the Development of Advanced Li-ion Batteries:a Review[J].Energy&Environmental Science,2011,4(9):3243-3262.
[3] BEAULIEU L Y,HATCHARD T D,BONAKDARPOUR A,et al.Reaction of Li with Alloythin Films Studied by in Situ AFM[J].Journal of the Electrochemical Society,2003,150(11):A1457-A1464.
[4] ZHANG Y,JIANG Y,LI Y,et al.Preparation of Nanographite Sheets Supported Si Nanoparticles by in Situ Reduction of Fumed SiO2 with Magnesium for Lithium ion Battery[J].Journal of Power Sources,2015,281:425-431.
[5] BC KIM,UONO H,SATO T,et al.Li-ion Battery Anodeproperties of Si-carbon Nanocomposites Fabricated by High Energy Multiring-type mill[J].Solid State Ionics,2004,172(1-4):33-37.
[6] HOLZAPFEL M,BUQA H,SCHEIFELE W,et al.A New Type of Nano-sized Silicon/Carbon Composite Electrode for Reversible Lithium Insertion[J].Chemical Communications,2005(12):1566-1568.
[7] DATTA M K,KUMTA P N.Silicon and Carbon based Composite Anodes for Lithium ion Batteries[J].Journal of Power Sources,2006,158(1):557-563.
[8] LEE J H,KIM W J.Self-Discharge Behaviors of Lithium/Sulfur Cells with Gel Polymer Electrolyte[J].Journal of Power Sources,2008,176:353-358.
[9] KANG J,CHEN Y N,WANG A L,et al.Synthesis,Characterization and Luminescent Properties of Europium Complexes with 2,4,6-tris-(2-pyridyl)-s-triazine as Highly Efficient Sensitizers[J].Luminescence,2016,30(8):1360-1366.
[10]ZHANG H,CAO G,YANG Y.Supercapacitors based on3DNanosTructured Electrodes[J].Springer New York,2011.
[11]KIM T,MO Y H,NAHM K S,et al.Carbon Nanotubes(CNTs)as a Buffer Layer in Silicon/CNTs Composite Electrodes for Lithium Secondary Batteries[J].Journal of Power Sources,2006,162(2):1275-1281.
[12]FENG X,YANG J,BIE Y,et al.Nano/micro-structured Si/CNT/C Composite from Nano-SiO2for High Power Lithium ion Batteries[J].Nanoscale,2014,6(21):12532.
[13]SU J,ZHAO J,LI L,et al.Three-dimensional Porous Si and SiO2 with in Situ Decorated Carbon Nanotubes as Anode Materials for Li-ion Batteries[J].ACS Applied Materials&Interfaces,2017,9(21):17807-17813.
[14]ZHANG M,HOU X,WANG J,et al.Interweaved Si@C/CNTs&CNFs Composites as Anode Materials for Liion Batteries[J].Journal of Alloys&Compounds,2014,588:206-211.
[15]KIM T,MO Y H,NAHM K S,et al.Kim,T.Mo,Y.H.Nahm,K.S.&Oh,S.M.Carbon Nanotubes(CNTs)as a Buffer Layer in Silicon/CNTs Composite Electrodes for Lithium Secondary Batteries[J].Journal of Power Sources,2006,162,1275-1281.
[16]WANG W,KUMTA P.Nanostructured Hybrid Silicon/Carbon Nanotube Heterostructures:Reversible High-Capacity Lithium-Ion Anodes[J].ACS Nano,2010,4(4):2233-2241.
[17]COHIER A,LAIK B,KIM K H,et al.High-Rate Capability Silicon Decorated Vertically Aligned Carbon Nanotubesfor Li-Ion Batteries[J].Advanced Materials,2012,24(19):2592-2597.
[18]HWANG T,LEE Y,KONG B,et al.Electrospun Core-Shell Fibers for Robust Silicon Nanoparticle-Based Lithium ion Battery Anodes[J].Nano Letters,2012,12(2):802-807.
[19]WANG B,LI X,ZHANG X,et al.Contact-Engineered and Void-Involved Silicon/Carbon Nanohybrids as Lithium ion Battery Anodes[J].Advanced Materials,2013,25(26):3560-3565.
[20]CHOU S L,WANG J Z,CHOUCAIR M,et al.Enhanced Reversible Lithium Storage in a Nanosize Silicon/Graphene Composite[J].Electrochemistry Communications,2010,12(2):303-306.
[21]LEE J K,SMITH K B,HAYNER C M,et al.Silicon Nanoparticles-Graphene Paper Composites for Li Ion Battery Anodes[J].Chemical Communications,2010,46(12):2025-2027.
[22]KO M,CHAE S,JEONG S,et al.Elastic a-silicon Nanoparticle Backboned Graphene Hybrid as a Self-compacting Anode for High-Rate Lithium ion Batteries[J].ACS Nano,2012,8(8):8591-8599.
[23]LUO J,ZHAO X,WU J,et al.Crumpled Graphene-Encapsulated Si Nanoparticles for Lithium Ion Battery Anodes[J].Journal of Physical Chemistry Letters,2012,3(13):1824-1829.
[24]MORI T,CHEN C J,HUNG T F,et al.Electrochemical Performance of Silicon Whisker and Carbon Nanofiber Composite Anode Electrochim.Acta[J].Physical Review,2015,165:166-172.
[25]LIU X,ZHANG J,SI W,et al.Sandwich Nanoarchitecture of Si/Reduced Graphene Oxide Bilayer Nanomembranesfor Li-Ion Batteries with Long Cycle Life[J].ACS Nano,2015,9(2):1198-205.
[26]XIAO Q F,GU M,YANG H,et al.Inward Lithium-ion Breathing of Hierarchically Porous Silicon Anodes[J].Nature Communications,2015,6:8844.
[27]YI R,DAI F,GORDIN M L,et al.Micro-sized Si-C Composite with Interconnected Nanoscale Building Blocks as High-performance Anodes for Practical Application in Lithium-ion Batteries[J].Advanced Energy Materials,2013,3(3):295-300.
[28]LU Z,LIU N,LEE H-W,et al.Nonfilling Carbon Coating of Porous Silicon Micrometer-sized Particles for Highperformance Lithium Battery Anodes[J].ACS Nano,2015,9(3):2540-2547.
[29]AN Y,FEI H,ZENG G,et al.Green,Scalable and Controllable Fabrication of Nanoporous Silicon from Commercial Alloy Precursors for High-energy Lithium-ion Batteries[J].ACS Nano,2018,12(5):4993-5002.
[30]OBROVAC M N,CHEVRIER V L.Alloy Negative Electrodes for Li-ion Batteries[J].Chemical Reviews,2014,114(23):11444-11502.
[31]CASIMIR A,ZHANG H,OGOKE O,et al.Silicon-based Anodes for Lithium-ion Batteries:Effectiveness of Materials Synthesis and Electrode Preparation[J].Nano Energy,2016,27:359-376.
[32]LI H,HUANG X J,CHEN L Q,et al.A High Capacity Nano-Si Composite Anode Material for Lithium Rechargeable Batteries[J].Electrochemical and Solid State Letters,1999,2(11):547-549.
[33]YOSHIO M,WANG H Y,FUKUDA K,et al.Carboncoated Si as a Lithium-ion Battery Anode Material[J].Journal of the Electrochemical Society,2002,149(12):A1598-A1603.
[34]QU J,LI H Q,HENRY J J,et al.Self-aligned Cu-Si Coreshell Nanowire Array as a High-performance Anode for Li-ion Batteries[J].Journal of Power Sources,2012,198:312-317.
[35]FU K,YILDIZ O,BHANUSHALI H,et al.Aligned Carbon Nanotube-silicon Sheets:a Novel Nano-architecture for Flexible Lithium ion Battery Electrodes[J].Advanced Materials,2013,25(36):5109-5114.
基本信息:
DOI：
中图分类号:TM912
引用信息:
[1]汪征东,陈娟,常海涛.锂离子电池硅基负极材料的研发进展[J].电池工业,2021,25(05):247-252.
基金信息: