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金属空气电池以活泼的轻质金属为负极,配合燃料电池中的空气电极为正极,所以也被称为金属半燃料电池。铝是地球上已知储量最多的金属元素,且具有非常高的能量密度,因此铝空气电池自发现以来就受到了广泛的关注。本文主要从铝电极、空气电极和电解液三个方面出发,对铝空气电池研究进展进行归纳介绍,并对铝空气电池的应用前景进行展望。
Abstract：Metal-air battery uses light and active metal as negative electrode and matches the positive air electrode in the fuel cell,which is also called metal semi-fuel cell.Aluminum is known as the most abundant metal element on the earth with high energy density,so aluminum air batteries have received a lot of attention in recent years.This work mainly summarizes the research progress of aluminum-air battery on aluminum electrode,air electrode,electrolyte and prospects the application prospects of aluminum air battery.
[1]HOPKINS B J,YANG S H,HART D P.Suppressing corrosion in primary aluminum-air batteries via oil displacement[J].Science,2018,362:658-661.
[2]LIU Y,SUN Q,LI W Z,et al.A comprehensive review on recent progress in aluminum-air batteries[J].Green Energy&Environment,2017,2(03):246-277.
[3]YANG H C,LI H C,LI J S,et al.The Rechargeable A-luminum Battery:Opportunities and Challenges[J].Angewandte Chemie International Edition,2019,58:2-21.
[4]李碧谕,东青,张佼,等.铝空气电池阳极材料的研究进展[J].中国材料进展,2016,35(11):849-855.
[5]MACDONALD D D,LEE K H,MOCCARI A,et al.Evaluation of Alloy Anodes for Aluminum-Air Batteries:Corrosion Studies[J].Corrosion Science,1998,44(9):652-657.
[6]秦学,李振亚.铝合金阳极活化机理研究进展[J].电源技术,2000,24(1):53-56.
[7]CHO Y-II,KALUBARME R S,JANG H,et al.Effect of alloying elements on the electrochemical characteristics of an Al alloy electrode for Al-air batteries in 4 MNaOH solution[J].Journal of the Korean Institute of Metals and Materials,2011,49(11):839.
[8]黄宇芬,侯玙杰,陈思宇,等.铝空气电池阳极材料的研制[J].化学工程师,2017,31(09):4-6+17.
[9]唐有根,刘小锋,宋永江.铝空气电池负极材料热处理的研究进展[J].功能材料,2008,5:47-50.
[10]贺俊光,文九巴,周旭东,等.冷变形对铝空气电池用阳极电化学性能的影响[J].腐蚀科学与防护技术,2013,25(03):229-232.
[11]FAN L,LU H.The effect of grain size on aluminum anodes for Al-air batteries in alkaline electrolytes[J].Journal of Power Source,2015,284:409-415.
[12]程新群.化学电源[M].北京:化学工业出版社,2018:245-247.
[13]GE X M,SUMBOJA A,WUU D,et al.Oxygen Reduction in Alkaline Media:From Mechanisms to Recent Advances of Catalysts[J].American Chemical Society Catalysis,2015,5(8):4643-4667.
[14]HAN J J,LI N,DE L L,et al.Preparation of Ag/C Catalysts for The O2,Electrode by The Ag(I)SCRM[J].Materials Chemistry&Physics,2009,115(2):685-689.
[15]HAN J J,LI N,LIU D L,et al.Studies on The Reduction Mechanism of Oxygen on Ag/C Catalysts in Alkaline Solutions[J].Journal of Fuel Cell Science&Technology,2013,10(6):1-4.
[16]ERIKSON H,SARAPUU A,SOLLA-GULLN J,et al.Recent progress in oxygen reduction electrocatalysis on Pd-based catalysts[J].Journal of Electroanalytical Chemistry,2016,780:327-336.
[17]CHEN R R,LI H X,CHU D,et al.Unraveling Oxygen Reduction Reaction Mechanisms on Carbon-Supported Fe-Phthalocyanine and Co-Phthalocyanine Catalysts in Alkaline Solutions[J].Journal of Physical Chemistry C,2009,113(48):20689-20697.
[18]XU S H,LI Z F,JI Y F,et al.A novel cathode catalyst for aluminum-air fuel cells:Activity and durability of polytetraphenylporphyrin iron(II)absorbed on carbon black[J].International Journal of Hydrogen,2014,39:20171-20182.
[19]XIANG F W,CHEN X H,YU J,et al.Synthesis of three-dimensionally ordered porous perovskite type LaMnO3for Al-air battery[J].Journal of Materials Science&Technology,2018,34(9):1532-1537.
[20]SUNTIVICH J H,GASTEIGER A,YABUUCHI H,et al.Design Principles for Oxygen Reduction Activity on Perovskite Oxide Catalysts for Fuel Cells and Metal-Air Batteries[J].Nature Chemistry,2011,3(8):647.
[21]CHENG F Y,SU Y,LIANG J,et al.MnO2-Based Nanostructures as Catalysts for Electrochemical Oxygen Reduction in Alkaline Media[J].Chemistry of Materials,2010,22(3):898-905.
[22]JIANG M,HE H,HUANG C,et al.Alpha-MnO2Nanowires/Graphene Composites with High Electrocatalytic Activity for Mg-Air Fuel Cell[J].Electrochimica Acta,2016,219:492-501.
[23]余祖孝,陈昌国,罗忠礼.铝-空气电池电解液的研究现状[J].化学研究与应用;2004,16(5):612-614.
[24]周育红,郭兴华,张生栋,等.影响铝阳极在NaCl溶液中放电性能因素的研究[J].材料科学与工艺,2007(02):192-196.
[25]杨寒雪.碱性溶液中二硫苏糖醇对AA5052铝合金阳极缓蚀作用的研究[A].中国腐蚀与防护学会缓蚀剂专业委员会.第二十届全国缓蚀剂学术讨论会论文集[C].中国腐蚀与防护学会缓蚀剂专业委员会:中国腐蚀与防护学会缓蚀剂专业委员会,2018:7.
[26]孙公权,高建新,王二东.一种铝空气电池电解质及其应用[P].中国专利:106887649A2017-12-16.
[27]马景灵,通帅,任凤章,等.L-半胱氨酸/ZnO缓蚀剂对3102铝合金在碱性溶液中电化学性能的影响[J].中国腐蚀与防护学报,2018,38(04):351-357.
[28]许超.铝空气电池电解液添加剂的研究[D].哈尔滨:哈尔滨工业大学化工学院,2018:1-4.
基本信息:
中图分类号:TM911.41
引用信息:
[1]阙奕鹏,齐敏杰,史鹏飞.铝空气电池研究进展[J].电池工业,2019,23(03):147-150.
2019-06-25
2019-06-25