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2004, 06, 320-324
国内外直接甲醇燃料电池研究进展
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发布时间: 2004-12-25
出版时间: 2004-12-25
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摘要:

甲醇以其能量密度高,来源丰富,价格低廉和储存方便等优点倍受关注,因此直接甲醇燃料电池已成为世界燃料电池研究的一个热点。介绍了二元合金、多元合金阳极催化剂、阴极催化剂和质子膜的研究现状;报导了国内外直接甲醇燃料电池样机达到的技术水平。

Abstract:

Methanol is an attractive fuel used in proton exchange membrane fuel cell, due to its high energy density, easy availability and storage. The new research and development status of anodic catalysts, ca-thodic catalysts, and proton exchange membrane were presented in this paper. The technical state of the prototype DMFC at home and abroad was introduced in detail.

参考文献

[1] Costamagna P, Srinivasan S. Quantum jumps in the PEM FC science and technology form the 1960s to the year 2000. [J]. J Power Source, 2001, 102(1 -2): 242-252.

[2]苏爱华,李长志,孙公权,等.Pt/C-SPE和Pt Ru/C-S PE膜电极上甲醇的催化氧化[J].电化学,1995,1(4):397-401.

[3]李旭光,邢巍,唐亚文,等.直接甲醇燃料电池阴极电催化剂的研究进展[J].化学通报,2003,8:521-527.

[4]周卫江,周振华,李文震,等.直接甲醇燃料电池阳极催化剂研究进展[J].化学通报,2003,4:228-234.

[5] Denis M C, Gouerie P, Guay.D, et al. Improvement of the high energy ball - milling preparation procedure of tolerant Pt and Ru containing catalysts for polymer electrolyte fuel cells. [J] J Applied Electrochemistry, 2000(11), 30: 1243-1253.

[6] Liu Renxuan, Eugene S S. Array membrane electrode assemblies for high throughput screening of direct methanol fuel cell anode catalysts [J] . Journal of Electroanalytical Chemistry, 2002,535(1-2): 49-55.

[7] Shubina T E, Koper M T M. Quantum - chemical calculations of CO and OH interacting with bimetallic surfaces[J]. Electrochemistry Acta, 2002, 47: 3 621 - 3 628.

[8] Hu L Q. Development of 40W PEM fuel cell engine for the passenger car and 80kW fuel cell engine for the city bus - the introduction of PEM fuel cell technology [C] 2nd Guangzhou Fuel Cell Conference [C]. Guangzhou, 2003. 27 - 35.

[9] Ren X M, Wilson M S, Gottesfeld S,et al. High performance direct methanol polymer electrolyte fuel cells [J] . J Elec-trochem Soc, 1996, 143(1): 12-15.

[10]刘长鹏,杨辉,邢巍,等.直接甲醇燃料电池中碳载Pt-TiO2阳极复合催化剂的研究[J].南京师范大学报(自然科学版),2001,24(2):55-66.

[11] Gotz M, Wendt H. Binary and ternary anode catalyst formulation including the elements W, Sn and Mo for PEMFCs operated on methanol for reformat gas[J] . Electrochem Acta, 1998,43(24): 3 637-3 644.

[12] Liu R X, Iddir H, Fan Q B, et al. Potential -dependent infrared absorption spectroscopy of adsorbed CO and X - ray photoelectron spectroscopy of arc - melted single - phase Pt, PtRu, PtOs, PtRuOs, and Ru electrodes[J] . J Physical Chemistry, 2000, 104(15): 3 518-3 531.

[13] Roth C, Gotz M, Fuess H. Synthesis and characterization of carbon-supported Pt-Ru-WOx catalysts by spectroscopic and diffraction methods[J] . J Applied Electrochemistry, 2001, 31 (7): 793-798.

[14] Gotz M, Wendt H. Composite electrocatalysts for anodic methanol and methanol - reformat oxidation [J] . J Applied Electrochemistry, 2001,31:811-817.

[15] Golabi S M, Nozad A. Electrocatalytic oxidation of methanol on electrodes modified by platinum microparticles dipersed into poly(o - phenylenediamine) film[J] . J Electroanal Chem, 2001,521: 16! - 167.

[16] Shukla A K, Neergat M, Bera P, et al. An XPS study on binary and ternary alloys of transition metals with platinized carbon and its bearing upon oxygen electroreduction in direct methanol fuel cells[J]. J Electroanal Chem, 2001, 504 (1): 111 -119.

[17] Drillet J F, Ee A, Friedemann J, et al. Oxgen reduction at Pt and Pt70Ni30in H2SO4/CH3OH solution[J] . Electrochem-istry Acta, 2002,47 (12): 1983 - 1988.

[18] Reeve R W, Cristensen P A, Hamnett A, et al. Mthanol tolerant oxygen reduction catalysts based on transition metal sulfides[J] . J Electrochem Soc, 1998, 145(10): 3 463 - 3 507.

[19] Tricoli V. Proton and methanol transport in poly(perf luoro-sulfonate) membranes containing Cs+ and H+ cations [J]. J Electrochem Soc, 1998, 145, 11: 3 798 - 3 701.

[20] Hong W H, Kim Y J, Choi W C, et al. Reducing methanol cross - over with Pd - plugged proton conductive membrane for a direct methanol fuel cells[A]. 2002 Fuel Cell Seminar [C]. California, 2002. 223 - 226.

[21] Si Y C, Lin J C, Kunz H R, et al. Nafion(r) -zirconium hydrogen phosphate composite membranes for high temperature direct methanol fuel cells(DMFC) [A] . 2002 Fuel Cell Seminar[C]. California, 2002. 185 - 188.

[22]李磊,张军,吴洪,等.直接甲醇燃料电池新型聚合物膜的研究[J].电化学,2002,8(2):177-181.

[23]史萌,邱新平,朱文涛,等.Nafion膜在直接甲醇燃料电池中的应用及改进[J].化学通报,2001,8:481-491.

[24] Zelenay P, Brosha E, Davey J, et al. Direct methanol fuel cells. Hydrogen, Fuel Cells and Infrastructure Technologies [A]. 2002 Fuel Cell Seminar[C]. California, 2002. 441 -446.

[25]李建玲,毛宗强.直接甲醇燃料电池研究现状及主要问题[J].电池,2001,31(1):36-39.

[26] Stolten D, Mergel J, Dohle H, et al. Development of directmethanol fuel cell stacks [A]. 2002 Fuel Cell Seminar [C].California, 2002. 1 004 - 1 007.

[27] Janssen H, Noelke M, Zwaygardt W, et al. DMFC systems:2. 5kW class in compact design[A]. 2002 Fuel Cell Semi-nar[C]. California, 2002. 367 - 370.

[28] Narayanan S R, Valdez T I, Kindler A, et al. Advances indirect methanol fuel cells for mobile and portable applicants[A] . 2002 Fuel Cell Seminar[C], California, 2002.1000 - 1 003.

[29] Kosek A, Cecelia C C, Hamdan M, et al. Portable directmethanol fuel cell systems [A] . 2002 Fuel Cell Seminar,[C]. California, 2002. 482 - 485.

[30] Dohle H, Mergel J, Schmitz H, et al. Development of a 2. 5kWclass DMFC stack[A]. 2002 Fuel Cell Seminar[C]. California,2002.328-331.

[31]王凤娥.直接甲醇燃料电池研究现状及技术进展[J].稀有金属,2002,26(6):497-501.

[32] Choi K H, Lee S A, Kim J R, et al. Direct liquid feed cellfor portable power source[A]. 2002 Fuel Cell Seminar[C].California, 2002. 1 008 - 1 010.

[33] Xing wei. Study of key materials for PEM and DM Fuel Cells[A]. 2nd Guangzhou Fuel Cell Conference[C]. Guangzhou,2003.

[34] Cunningham J, Moore R, Badrinarayanan P, el al. DMFCresults and characlerizalion for a 10kW(net) system, with100℃ stack operation[A] . 2002 Fuel Cell Seminar[C] .California, 2002. 363 - 366.

基本信息:

中图分类号:TM911.4

引用信息:

[1]黄红良,隋静,陈红雨,李伟善.国内外直接甲醇燃料电池研究进展[J].电池工业,2004(06):320-324.

发布时间:

2004-12-25

出版时间:

2004-12-25

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