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钠离子电池是一种具有广泛应用前景的新型电化学储能技术。本文聚焦石油沥青基硬碳在钠离子电池负极的应用，首先介绍了该材料因来源广、成本低而备受关注的背景，通过统计2010—2024年论文数量及专利申请情况，展示了该领域的研究热度，进而阐述了包括工艺流程、原料预处理、碳化反应与改进方法的主流技术路线。但该技术仍面临原料、碳化效率、结构性能平衡及规模化生产等挑战。当前研究主要集中在前驱体、沥青转化和碳化等方面。随着研究的不断深入与持续推进，通过对制备工艺的进一步优化以及对材料结构与性能关系的深度理解，石油沥青基硬碳负极材料有望在钠离子电池及更大范围的储能领域实现产业化应用。
Abstract：Sodium-ion batteries represent a promising new electrochemical energy storage technology with broad application prospects. This paper focuses on the application of petroleum asphalt-based hard carbon in sodium-ion batteries anode. Firstly, it introduces the background of this material's growing attention due to its wide availability and low cost, followed by a statistical analysis of research trends from 2010 to 2024 through examining the number of academic papers and patent applications. The paper then elaborates on mainstream technical approaches including process flow, raw material pretreatment, carbonization reaction, and improvement methods. However, challenges remain in raw materials sourcing, carbonization processes, structural-property balance, and large-scale production. Currently, the research primarily concentrates on precursors, asphalt conversion, and carbonization techniques. Continuous advancements in preparation processes and deeper understanding of material structureproperty relationships are driving progress. Petroleum asphalt-based hard carbon anode materials is expected to achieve industrial application in sodium-ion batteries and broader energy storage field.
[1] MENG Q W,CHEN B Y,JIAN W B,et al. Hard carbon anodes for sodium-ion batteries:Dependence of the microstructure and performance on the molecular structure of lignin[J].Journal of Power Sources,2023,581:233475.
[2]李晋，王青松，孔得朋，等．锂离子电池储能安全评价研究进展[J]．储能科学与技术，2023,12(7):2282-2301.
[3]江晨，孙威，王立清，等．沥青包覆工艺在锂电池负极材料中的研究进展[J]．电池工业，2023,27(5):266-270.
[4] ZHANG J K,XIANG H X,CAO Z W,et al.Research progress of lignin-derived materials in lithium/sodium ion batteries[J]. Green Energy&Environment,2025,10(2):322-344.
[5]宁汇，王路海，何盛宝，等．石油沥青基碳材料的电化学应用研究进展[J]．石油炼制与化工，2021,52(10):38-45.
[6] ZHANG Y,FANG H Q,GUAN L,et al. Effect of asphalt component distribution characteristics in layered porous carbon on performance of supercapacitors[J].Journal of Power Sources,2024,593:233966.
[7]陈涛，吴吉昊，车晓刚，等．改性沥青基硬碳材料的可控制备及其储钠性能[J]．洁净煤技术，2023,29(2):92-98.
[8]和凤祥，吕晗，陈雪，等．沥青基硬碳材料制备方法及电化学性能初探[J]．炭素，2021(1):31-35.
[9] SHENG L,WEI P,MA H,et al. A molecular-scale regulation strategy for designing asphalt-based hard carbon for superior sodium storage[J].Journal of Materials Chemistry A,2024,12(45):31480-31491.
[10] QIAN W Y,ZHOU X Y,LIU X Y,et al.Breakage of the dense structure of coal precursors increases the plateau capacity of hard carbon for sodium storage[J].Chemical Science,2024,16(1):104-112.
[11] ZENG H T,KANG W W,XING B L,et al. Microstructure modulation of hard carbon derived from longflame coal to improve electrochemical sodium storage performances[J].Fuel Processing Technology,2025,267:108159.
[12] ZHAO C J,GUO H M,ZHU B B,et al.Epoxy resinderived N,P co-doping hard carbon with improved yield and anode performance in Li-ion battery[J]. Ionics,2024,30(4):1971-1981.
[13]罗治江，戴勇，蒲海源，等．石油沥青质分离纯化及其分子结构研究方法[J]．河北化工，2012(11):47-51.
[14] TIAN M L,LIU H T,CUI J,et al. Mechanism of highly efficient oil removal from spent hydrodesulfurization catalysts by ultrasound-assisted surfactant cleaning methods[J].Journal of Hazardous Materials,2024,472:134514.
[15]申兴海，沈海涛，沈本贤，等．FCC汽油萃取蒸馏脱硫效果[J]．华东理工大学学报（自然科学版），2011,37(4):416-423.
[16] WEI W,JIANG C G. Optimizing the preparation process of refined asphalt based on the response surface and preparation of needle coke[J]. ACS Omega,2024,9(11):13239-13251.
[17]朱豫飞，任相坤，金嘉璐，等．一种煤与石油共同加工生产优质发动机燃料的方法：CN101220287B[P].2010-11-10.
[18] JIN Z H,WANG B D,MA L,et al.Air pre-oxidation induced high yield N-doped porous biochar for improving toluene adsorption[J]. Chemical Engineering Journal,2020,385:123843.
[19] LIU D D,GAO J H,CAO Q X,et al.Improvement of activated carbon from Jixi bituminous coal by air preoxidation[J].Energy&Fuels,2017,31(2):1406-1415.
[20] ZHU Y W,GAO J H,SUN F,et al.Influence of coal preoxidation on the porosity of the activated carbons with steam activation[C]//Cleaner Combustion and Sustainable World.Berlin,Heidelberg:Springer Berlin Heidelberg,2013:897-903.
[21] TAMMELA P,IURCHENKOVA A,WANG Z H,et al. Laser irradiation of photothermal precursors-a novel approach to produce carbon materials for supercapacitors[J].ChemSusChem,2024,17(11):e202301471.
[22] GUO Z Q,XU X Q,ZHU D Q,et al.Clean preparation of formed coke from semi-coke by the carbonated consolidation process[J].ACS Omega,2023,8(30):27398-27409.
[23]叶冉，詹亮，乔文明，等．高温热处理对高比表面积活性炭孔结构及电极性能的影响[J]．中国科技论文在线，2009,4(6):400-403.
[24] ZHU S,GUAN C,WU Y T,et al.Upgraded structure and application of coal-based graphitic carbons through flash joule heating[J].Advanced Functional Materials,2024,34(39):2403961.
[25] WU S Y,GU J,ZHANG X,et al.Variation of carbon crystalline structures and CO2 gasification reactivity of Shenfu coal chars at elevated temperatures[J]. Energy&Fuels,2008,22(1):199-206.
[26] WANG D Y, WANG Q.Nitrogen-doped graphene prepared by high-temperature carbonization of polydopamine film[J]. Academic Journal of Materials&Chemistry,2023,4(2):38-44.
[27]刘占军，郭全贵，史景利，等．制备工艺对炭/石墨密封材料性能及其结构的影响[J]．炭素技术，2010,29(4):1-4,24.
[28] Niemeier R. Patty's Toxicology:Petroleum,coal tar,and related products[M]. Wiley,2001:325-370.
[29] LAI S R,LI S J,XU Y L,et al.Preparation,characterization,and performance evaluation of petroleum asphalt modified with bio-asphalt containing furfural residue and waste cooking oil[J].Polymers,2022,14(9):1683.
[30] LI Z M,WEI T,PAN J M,et al.Physicochemical preand post-treatment of coking wastewater combined for energy recovery and reduced environmental risk[J].Journal of Hazardous Materials,2023,447:130802.
[31] HUAN C G,WANG Q D,LI X Q,et al. Soluble carbon source recovery using preconditioning coagulants for applicable short-term fermentation of waste activated sludge in WWTPs[J].Environmental Research,2024,248:118409.
[32] YUAN M Y,YU S Z,WANG K F,et al.Ultrafast synthesis of hard carbon for high-rate and low-temperature sodium-ion storage through flash Joule heating[J].Solid State Ionics,2024,414:116622.
[33] JIN Y,SUN S X,OU M Y,et al. High-performance hard carbon anode:Tunable local structures and sodium storage mechanism[J].ACS Applied Energy Materials,2018,1(5):2295-2305.
[34] LU Y X,ZHAO C L,QI X G,et al. Pre-oxidationtuned microstructures of carbon anodes derived from pitch for enhancing Na storage performance[J].Advanced Energy Materials,2018,8(27):1800108.
[35] XIONG Z Y,YUE L,ZHANG Y,et al.Structural regulation of asphalt-based hard carbon microcrystals based on liquid-phase crosslinking to enhance sodium storage[J].Journal of Colloid and Interface Science,2024,658:610-616.
[36] LI Y M,MU L Q,HU Y S,et al.Pitch-derived amorphous carbon as high performance anode for sodium-ion batteries[J]. Energy Storage Materials,2016,2:139-145.
[37] WANG H,LIU S T,LEI C,et al.P-doped hard carbon material for anode of sodium ion battery was prepared by using polyphosphoric acid modified petroleum asphalt as precursor[J].Electrochimica Acta,2024,477:143812.
[38] XUE H T,SUN Q,LU R F,et al. Pyrolysis of coal pitch-infused melamine foam to construct N-doped carbon anodes for high-performance sodium-ion battery[J].Journal of Electroanalytical Chemistry,2021,902:115809.
[39] LI Y M,HU Y S,LI H,et al.A superior low-cost amorphous carbon anode made from pitch and lignin for sodium-ion batteries[J].Journal of Materials Chemistry A,2016,4(1):96-104.
[40] ZHAO Y,CONG Y,NING H,et al.Petroleum-pitchbased carbon nanocages encapsulated few-layer MoS2with S vacancies for a high-performance sodium-ion battery[J].Energy&Fuels,2023,37(6):4641-4649.
[41] WANG Y W,XIAO N,WANG Z Y,et al. Rational design of high-performance sodium-ion battery anode by molecular engineering of coal tar pitch[J]. Chemical Engineering Journal,2018,342:52-60.
[42] WU B Y,SUN H,LI X X,et al. Petroleum pitch derived hard carbon via NaCl-template as anode materials with high rate performance for sodium ion battery[J].Frontiers of Chemical Science and Engineering,2024,18(7):73.
[43] HAN L,LI Z M,YANG F,et al.Enhancing capacitive storage of carbonaceous anode by surface doping and structural modulation for high-performance sodium-ion battery[J].Powder Technology,2021,382:541-549.
基本信息:
DOI：10.19996/j.cnki.ChinBatlnd.2025.05.012
中图分类号:TQ127.11;TM912
引用信息:
[1]高志虹,滑夏.钠离子电池用石油沥青基硬碳负极的研究进展[J].电池工业,2025,29(05):418-426.DOI:10.19996/j.cnki.ChinBatlnd.2025.05.012.
基金信息: