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能源枯竭引发了寻找替代能源的热潮,氢气作为一种清洁能源引起了人们的广泛关注,尤其关注于电解水制取氢气,因此开发高效、稳定、廉价的电解水析氢的催化剂就成为研究热点。本文综述了铂(Pt)族元素中最便宜的钌和钌基材料作为高效电催化剂在电解水析氢反应中的研究进展,展望了钌和钌基材料在电解水析氢反应中的产业化应用前景。
Abstract：The search for alternative energy caused by the depletion of energy makes the whole world focus on electrolytic hydrogen evolution,which is a green and environmentally friendly method of hydrogen production.Therefore,the development of highly efficient catalysts for hydrogen evolution reaction(HER)has become a top priority.Herein,we reviewed the cheapest element in Pt group elements-ruthenium(Ru)and Ru-based material as highly efficient electrocatalyst for HER,followed by a summary and outlook for the research of this Ru-based electrocatalyst.
[1]HUANG J,LI Y,XIA Y,et al.Flexible cobalt phosphide network electrocatalyst for hydrogen evolution at all pHvalues[J].Nano Research,2017,10(3):1010-1020.
[2]ZHANG C,YANAGISAWA K,TAO H,et al.Oxygen Reduction Activity and Methanol Resistance of Ru-based Catalysts Prepared by Solvothermal Reaction[J].Catalysis Letters,2012,142(9):1128-1133.
[3]ZOU X,ZHANG Y.Noble metal-free hydrogen evolution catalysts for water splitting[J].Chemical Society Reviews,2015,44(15):5148-5180.
[4]DINCER I.Green methods for hydrogen production[J].International Journal of Hydrogen Energy,2012,37(2):1954-1971.
[5]BADWAL S P S,GIDDEY S,MUNNINGS C.Hydrogen production via solid electrolytic routes[J].Wiley Interdisciplinary Reviews:Energy and Environment,2013,2(5):473-487.
[6]TURNER J A.Sustainable Hydrogen Production[J].Science,2004,305(5686):972.
[7]GRAETZ J.New approaches to hydrogen storage[J].Chemical Society Reviews,2009,38(1):73-82.
[8]URSUA A,GANDIA L M,SANCHIS P.Hydrogen Production From Water Electrolysis:Current Status and Future Trends[J].Proceedings of the IEEE,2012,100(2):410-426.
[9]KOTHARI R,BUDDHI D,SAWHNEY R L.Comparison of environmental and economic aspects of various hydrogen production methods[J].Renewable and Sustainable Energy Reviews,2008,12(2):553-563.
[10]LANG Y,ARNEPALLI R R,TIWARI A.A Review on Hydrogen Production:Methods,Materials and Nanotechnology[J].Journal of Nanoscience and Nanotechnology,2011,11(5):3719-3739.
[11]GUO Y,PARK T,YI J W,et al.Nanoarchitectonics for Transition-Metal-Sulfide-Based Electrocatalysts for Water Splitting[J].Advanced Materials,2019,31(17):1807134.
[12]ZHANG J,ZHANG Q,FENG X.Support and Interface Effects in Water-Splitting Electrocatalysts[J].Advanced Materials,2019,31:1808167.
[13]YOU B,TANG M T,TSAI C,et al.Enhancing Electrocatalytic Water Splitting by Strain Engineering[J].Advanced Materials,2019,31(17):1807001.
[14]ZHANG X,KLAVER P,SANTEN R V,et al.Oxygen Evolution at Hematite Surfaces:The Impact of Structure and Oxygen Vacancies on Lowering the Overpotential[J].The Journal of Physical Chemistry C,2016,120(32):18201-18208.
[15]TONG S S,WANG X J,LI Q C,et al.Progress on Electrocatalysts of Hydrogen Evolution Reaction Based on Carbon Fiber Materials[J].Chinese Journal of Analytical Chemistry,2016,44(9):1447-1457.
[16]COOK T R,DOGUTAN D K,REECE S Y,et al.Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds[J].Chemical Reviews,2010,110(11):6474-6502.
[17]徐文策,王红霞.非晶非贵金属催化剂的研究进展及展望[J].催化学报,2017,38(6):991-1005.
[18]QI K,YU S,WANG Q,et al.Decoration of the inert basal plane of defect-rich MoS2 with Pd atoms for achieving Pt-similar HER activity[J].Journal of Materials Chemistry A,2016,4(11):4025-4031.
[19]XIE J,ZHANG H,LI S,et al.Defect-Rich MoS2Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution[J].Advanced Materials,2013,25(40):5807-5813.
[20]CHENG L,HUANG W,GONG Q,et al.Ultrathin WS2Nanoflakes as a High-Performance Electrocatalyst for the Hydrogen Evolution Reaction[J].Angewandte Chemie International Edition,2014,53(30):7860-7863.
[21]JIANG N,TANG Q,SHENGM,et al.Nickel sulfides for electrocatalytic hydrogen evolution under alkaline conditions:a case study of crystalline NiS,NiS2,and Ni3S2nanoparticles[J].Catalysis Science Technology,2016,6(4):1077-1084.
[22]JASION D,BARFOROUSH J M,QIAO Q,et al.LowDimensional Hyperthin FeS2Nanostructures for Efficient and Stable Hydrogen Evolution Electrocatalysis[J].American Chemical Society Catalysis,2015,5(11):6653-6657.
[23]LIU Z,ZHAO L,LIU Y,et al.Vertical nanosheet array of 1Tphase MoS2for efficient and stable hydrogen evolution[J].Applied Catalysis B:Environmental,2019,246:296-302.
[24]XIA Y,HUANG J,WU W,et al.Sulfur-Doped Rhenium Selenide Vertical Nanosheets:A High-Performance Electrocatalyst for Hydrogen Evolution[J].ChemCatChem,2018,10(19):4424-4430.
[25]LIU T,LI P,YAO N,et al.CoP-Doped MOF-Based Electrocatalyst for pH-Universal Hydrogen Evolution Reaction[J].Angewandte Chemie International Edition,2019,58(14):4679-4684.
[26]DU H,KONG R M,GUO X,et al.Recent progress in transition metal phosphides with enhanced electrocatalysis for hydrogen evolution[J].Nanoscale,2018,10(46):21617-21624.
[27]SHI Y,ZHANG B.Recent advances in transition metal phosphide nanomaterials:synthesis and applications in hydrogen evolution reaction[J].Chemical Society Reviews,2016,45(6):1529-1541.
[28]XIAO P,CHEN W,WANG X.A Review of PhosphideBased Materials for Electrocatalytic Hydrogen Evolution[J].Advanced Energy Materials,2015,5(24):1500985.
[29]ZHONG Y,XIA X,SHI F,et al.Transition Metal Carbides and Nitrides in Energy Storage and Conversion[J].Advanced Science,2016,3(5):1500286.
[30]PENG X,PI C,ZHANG X,et al.Recent progress of transition metal nitrides for efficient electrocatalytic water splitting[J].Sustainable Energy Fuels,2019,3(2):366-381.
[31]XING Z,LI Q,WANG I,et al.Self-supported nickel nitride as an efficient high-performance threedimensional cathode for the alkaline hydrogen evolution reaction[J].Electrochimica Acta,2016,191(841-845).
[32]MA T Y,DAI S,JARONIEC M,et al.Metal-Organic Framework Derived Hybrid Co3O4-Carbon Porous Nanowire Arrays as Reversible Oxygen Evolution Electrodes[J].Journal of the American Chemical Society,2014,136(39):13925-13931.
[33]ZHENG Z,LI N,WANG C Q,et al.Electrochemical synthesis of Ni-S/CeO2composite electrodes for hydrogen evolution reaction[J].Journal of Power Sources,2013,230:10-14.
[34]CHENG N,STAMBULA S,WANG D,et al.Platinum single-atom and cluster catalysis of the hydrogen evolution reaction[J].Nature Communications,2016,7:13638.
[35]ZHENG Y,JIAO Y,ZHU Y,et al.High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst[J].Journal of the American Chemical Society,2016,138(49):16174-16181.
[36]YANG J,CHEN B,LIU X,et al.Efficient and Robust Hydrogen Evolution:Phosphorus Nitride Imide Nanotubes as Supports for Anchoring Single Ruthenium Sites[J].Angewandte Chemie International Edition,2018,57(30):9495-9500.
[37]YAO Y,HU S,CHEN W,et al.Engineering the electronic structure of single atom Ru sites via compressive strain boosts acidic water oxidation electrocatalysis[J].Nature Catalysis,2019,2(4):304-313.
[38]YU J,GUO Y,MIAO S,et al.Spherical Ruthenium Disulfide-Sulfur-Doped Graphene Composite as an Efficient Hydrogen Evolution Electrocatalyst[J].American Chemical Society Applied Materials Interfaces,2018,10(40):34098-34107.
[39]WANG K,CHEN Q,HU Y,et al.Crystalline Ru0.33Se Nanoparticles-Decorated TiO2 Nanotube Arrays for Enhanced Hydrogen Evolution Reaction[J].Small,2018,14(37):1802132.
[40]PU Z I,AMIINU S,KOU Z,et al.RuP2-Based Catalysts with Platinum-like Activity and Higher Durability for the Hydrogen Evolution Reaction at All pH Values[J].Angewandte Chemie International Edition,2017,56(38):11559-11564.
[41]QIN Q,JANG H,CHEN L,et al.Low Loading of RhxPand RuP on N,P Codoped Carbon as Two Trifunctional Electrocatalysts for the Oxygen and Hydrogen Electrode Reactions[J].Advanced Energy Materials,2018,8(29):1801478.
[42]YU J,GUO Y,SHE S,et al.Bigger is Surprisingly Better:Agglomerates of Larger RuP Nanoparticles Outperform Benchmark Pt Nanocatalysts for the Hydrogen Evolution Reaction[J].Advanced Materials,2018,30(39):1800047.
基本信息:
中图分类号:TQ116.2;O643.36
引用信息:
[1]姚俊杰,唐佳易,杨志娟,等.电解水制氢中钌基电催化剂的研究进展[J].电池工业,2019,23(03):151-156.
基金信息:
江苏省碳基功能材料与器件高技术研究重点实验室开放课题(批准号:KJS1807)
2019-06-25
2019-06-25