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锂离子电池是现如今通信行业、电动汽车行业、航天航空以及军事领域的主要能源。但由于其首次不可逆容量损失过高和首次库伦效率过低阻碍了锂离子电池的进一步发展,难以满足现如今社会生产生活的发展要求,人们急于寻求一种有效的方法来解决目前的困境。预锂化技术的兴起对锂离子电池能量密度的提升、不可逆容量损失的改善以及首次库伦效率的提高提供了一条有效途径,为锂离子电池的发展注入了生机。在首次充放电之前在负极补充活性锂或通过正极向负极提供活性锂以弥补负极上因氧化还原反应而造成的锂损失,经过多年的研究和发展,已经研究出多方向多类型的预锂化技术。本文重点介绍了负极补锂、正极补锂的一些方法,并展望了未来预锂化技术的发展方向。
Abstract：Lithium-ion battery is the main energy source in the communication industry,electric vehicle industry,aerospace,and military field.However,because its first irreversible capacity loss is too high and its first coulombic efficiency is too low,it hinders the further development of lithium-ion batteries,and it is difficult to meet the development requirements of today's social production and life.The rise of pre-lithiation technology provides an effective way to improve the energy density,irreversible capacity loss,and the first coulombic efficiency of lithium-ion batteries,and injects vitality into the development of lithium-ion batteries.After years of research and development,multi-directional and multi-type pre-lithiation technologies have been developed to supplement active lithium at the negative electrode or provide active lithium to the negative electrode through the positive electrode to compensate for lithium loss caused by a redox reaction.In this paper,some methods of lithium supplementation in anode and cathode are introduced,and the development direction of pre-lithiation technology in the future has been prospected.
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基本信息:
中图分类号:TG146.26;TM912
引用信息:
[1]朱如强,李志伟,孙浩,等.锂离子电池快速发展的关键：预锂化技术[J].电池工业,2021,25(04):209-215.
2021-08-25
2021-08-25