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硫化物固态电解质与聚合物、氧化物固态电解质相比,在离子电导率、热稳定性等方面表现出较大优势,因此获得了广泛的关注。然而硫化物固态电解质与正/负极界面相容性问题且化学性质不稳定,这些都制约着其在全固态电池中的应用。通常,通过电极材料改性,电极包覆和元素掺杂等方法能够有效改善这些问题。介绍了硫化物固态电解质的主要类型,讨论了目前其应用中存在的问题,分析了硫化物固态电池优化的方法及其最新研究进展,最后对硫化物固态电解质在全固态电池中的应用进行了展望,提出了今后研究中应重点关注的技术和方向。
Abstract:Inorganic sulfide solid electrolytes show great advantages in ionic conductivity,thermal stability and other aspects when compared with polymer and oxide solid electrolytes,so they have been widely concerned.However,the poor compatibility between sulfide solid electrolyte and positive/negative electrode interface and the unstable chemical properties restrict its application in ASSBs.These problems can be effectively improved by modifying electrode materials,coating electrode and element dopingI.nsummary,this paper introduces and discusses the main types of sulfide solid electrolytes,remaining problems,and new research progress of optimization methods for ASSBs.Finally,the technology and direction of sulfide solid electrolyte research in ASSBs are discussed.
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基本信息:
中图分类号:TM912
引用信息:
[1]秦志光,顾正建.硫化物固态电解质在全固态电池中的应用研究进展[J].电池工业,2021,25(06):329-335.
基金信息:
江苏省市场监督管理局科技计划项目(KJ207520)
2021-12-25
2021-12-25