nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
2026, 02, v.30 131-136
锂离子电池高温存储衰减机理研究
基金项目(Foundation):
邮箱(Email):
DOI: 10.19996/j.cnki.ChinBatlnd.2026.02.003
投稿时间: 2025-05-06
投稿日期(年): 2025
修回时间: 2025-05-26
终审时间: 2025-05-28
终审日期(年): 2025
审稿周期(年): 1
发布时间: 2025-06-06
出版时间: 2025-06-06
网络发布时间: 2025-06-06
移动端阅读
摘要:

本文研究了软包三元锂离子电池在高温存储过程中的容量衰减机理。借助内置参比电极,测量存储不同时间的全电池和正负极充放电曲线。通过微分容量(IC)曲线、微分电压(DV)曲线分析和电压重构法研究了正负极的衰减过程及其对全电池衰减的贡献。结果显示,高温60℃存储48天的软包三元锂离子电池正极、负极活性物质的质量和活性锂的含量分别损失6.32%、11.04%和7.02%。本研究使用的方法可推广应用于不同类型的锂离子电池中。

Abstract:

This paper investigates the capacity degradation mechanism of pouch ternary lithium-ion batteries during high-temperature storage. With the help of built-in reference electrode, the charge/discharge curves of the full cell and positive and negative electrodes stored for different times were measured. Through incremental capacity(IC), differential voltage(DV) curves analysis, and voltage reconstruction methods, We systematically studied the attenuation process of positive and negative electrodes and their contribution to the full cell. The results show that after 48 days of storage at 60 ℃, the losses of positive and negative active materials and the active lithium in the pouch ternary lithium-ion battery are 6.32%, 11.04%, and 7.02%, respectively.This method can be extended to various types of lithium-ion batteries.

参考文献

[1]SHEN W,WANG N,ZHANG J,et al.Heat generation and degradation mechanism of lithium-ion batteries during high-temperature aging[J].ACS Omega,2022,7(49):44733-44742.

[2]SINHA N N,SMITH A J,BURNS J C,et al.The use of elevated temperature storage experiments to learn about parasitic reactions in wound LiCoO2∕Graphite cells[J].Journal of the Electrochemical Society,2011,158(11):A1194-A1201.

[3]LIU J W,YUE M,WANG S Q,et al.A review of per‑formance attenuation and mitigation strategies of lithiumion batteries[J].Advanced Functional Materials,2022,32(8):2107769.

[4]KASSEM M,BERNARD J,REVEL R,et al.Calendar aging of a graphite/LiFePO4 cell[J].Journal of Power Sources,2012,208:296-305.

[5]OUYANG D X,WENG J W,CHEN M Y,et al.Elec‑trochemical and thermal characteristics of aging lithiumion cells after long-term cycling at abusive-temperature environments[J]. Process Safety and Environmental Protection,2022,159:1215-1223.

[6]郭桐,刘涛,方德宇,等.锂离子电池健康评估研究进展[J].电池工业,2023,27(1):48-54.

[7]KEIL P,JOSSEN A.Calendar aging of NCA lithiumion batteries investigated by differential voltage analysis and coulomb tracking[J].Journal of the Electrochemical Society,2017,164(1):A6066-A6074.

[8]TOBISHIMA S,YAMAKI J,HIRAI T. Safety and capacity retention of lithium ion cells after long periods of storage[J].Journal of Applied Electrochemistry,2000,30(4):405-410.

[9]LIU W G,ZHENG J Q,ZHANG Z,et al.The capacity decay mechanism of the 100%SOC LiCoO2/graphite battery after high-temperature storage[J]. Journal of Power Sources,2023,580:233330.

[10]LEWERENZ M,WARNECKE A,SAUER D U.Postmortem analysis on LiFePO4|Graphite cells describing the evolution&composition of covering layer on anode and their impact on cell performance[J]. Journal of Power Sources,2017,369:122-132.

[11]ZHANG B D,ZHANG K,WU X H,et al.Decoupling the failure mechanism of Li-rich layered oxide cathode during high-temperature storage in pouch-type full-cell:A practical concern on anionic redox reaction[J].Advanced Energy Materials,2025,15(10):2404391.

[12]夏玉佳,陈丹丹,宋林霏,等.过渡金属溶出对电池循环影响[J/OL].电池工业,1-7[2025-06-04].http://kns.cnki. net/kcms/detail/32.1448. TM. 20241118.1533.002.html.

[13]SHEN C Y,ZENG Y X,WU Q,et al.Revealing hightemperature storage degradation mechanism in Li Ni0.5Mn1.5O4//graphite pouch cell[J].Journal of Energy Storage,2025,121:116591.

[14]刘宇隆,娄忠良,宋韶灵,等.LMO和NMC混合正极动力锂离子电池的衰减机理[J].汽车安全与节能学报,2016,7(3):313-321.

[15]WANG F F,TANG S J,HAN X B,et al. A voltage reconstruction model for lithium-ion batteries considering the polarization process[J].Journal of Power Sources,2023,588:233744.

基本信息:

DOI:10.19996/j.cnki.ChinBatlnd.2026.02.003

中图分类号:TM912

引用信息:

[1]陈丹丹,夏玉佳,宋林霏.锂离子电池高温存储衰减机理研究[J].电池工业,2026,30(02):131-136.DOI:10.19996/j.cnki.ChinBatlnd.2026.02.003.

投稿时间:

2025-05-06

投稿日期(年):

2025

修回时间:

2025-05-26

终审时间:

2025-05-28

终审日期(年):

2025

审稿周期(年):

1

发布时间:

2025-06-06

出版时间:

2025-06-06

网络发布时间:

2025-06-06

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文