| 467 | 41 | 159 |
| 下载次数 | 被引频次 | 阅读次数 |
LiNiO2被认为是最有希望代替LiCoO2的锂离子电池正极材料。介绍了LiNiO2的结构特征,报导了关于LiNiO2的结构相变和循环伏安方面的研究进展;综述了LiNiO2的各种制备方法及其优缺点;介绍了LiNiO2掺杂改性的方法以及在这方面的研究进展。
Abstract：Lithium nickel oxides were promising candidates for substitation of LiNiO2 as the cathode materials for Li-ion batteries. The crystal, structures, phase transformations and the voltage-current characteristics of LiNiO2 were described in detail. The synthesis methodes of the layer LiNiO2 and the modifications methodes by dopping with other ions were reviewed in this paper.
[1] Levi M D, Gamoisky K , Aubach D, et al. On electrochemical impedance measurements of LiCo0.2Ni0.8O2 and LiNiO2 intercalation electrodes[J]. J Electrochim Acta,2000,45: 1 781-1 789.
[2] Croguennee L, Pouilleri C, Delmas C. NiO2 obtained by electrochemical lithium deintercalation from lithium nichelate: structural modification[J]. J Electrochem Soc, 2000, 147 (4): 1 314-1 321.
[3]高虹,等.锂离子电池正极材料LiNiO2的制备和研究[J].电源技术,1999,23(6):353-357.
[4] Yamada S, Fujiwara M, Kanda M. Synthesis and properities ofLiNiO2 as cathode material for secondary battery [J]. J PowerSources, 1995,54:209-215.
[5] Kalyani P, Kalaiselvi N, Renganathan N G. Microwave-assistedsynthesis of LiNiO2-a preliminary investigation[J] . J PowerSources,2003 ,123(1): 53-60.
[6] Peng Z S,Wan C R,Jiang C Y. Synthesis by sol-gel processand characterization of LiCoO2 cathode material [J] .J Power Sources, 1998, 72: 215-220.
[7] Lee Yun Sung, Sun Yang Kook,Nahm Kee Suk. Synthesis and characterization of LiNiO2 cathode material prepared by an adiphic acid-assisted sol-gel method for lithium secondary batteries [J]. Solid State Ionics, 1999,118: 159-168.
[8]应皆荣,万春荣,姜长印,等.高密度球形LiNi0.8Co0.2O2的制备及性能[J].清华大学学报,2001,41:75-77.
[9] Chaoi R V, Prado F, Manthium A. Structural instability of delithiated Li1-xNi1-yCoyO2 cathodes[J] . J Electrochem Soc, 2001,148(1): 49-53.
[10] Tey G T K, Shiu R F, Subramanian V, et al. LiNi0.8Co0.2 cathode materials synthesized by the maleic acid assisted sol-gel method for lithium batteries [J] . J Power Sources,2002, 103: 265-272.
[11] Chaoi Y M, Pyun S, Moon S. Effects of cation mixing on the electrochemical lithium intercalation reaction into porous Li1-yNi1-yCoyO2 electrodes[J] . Solid State Ionics, 1996, 89: 43-51.
[12] Kyoo-Seung Han, Seung-wan song, Hirofumi fujra, et al. Single-step fabrication of Li1-xNi1+xO2 and LiCoO2 films by soft solution-process at 20-200 ℃ [J] . Solid State Ionics, 2000, 135:273-276.
[13] JuniChi Maruta. Low-temperature synthesis of lithium niche-late positive active material from nickel hydroxide for lithium cells[J]. J Power Sources, 2000, 90: 89-94.
[14] Hwang B J, Santhanam R, Chen C H. Effect of synthesis conditions on electrochemical properties of LiNi1-yCoyO2 cathode for lithium rechargeable battery [J] .J Power Sources, 2002, 5059: 1-9.
[15] Myoung Youp song, ryong Lee, lkhyun Kwon. Sol-gel method and electrochemical properties of LiNi1-yAlyO2 cathode materials for lithium secondary battery [J] . Solid State Ionics,2003, 156:319-328.
[16] Ohzuku T, Ueda A, Kouguchi M. Synthesis and characterization of LiAl1/4Ni3/4O3(R3m) for lithium-ion (shuttlecock) battery [J]. Electrochem Soc, 1995, 143(12): 4 033-4 039.
[17] Arai H, Okada S, Sakurai Y, et al. Electrochemical and thermal behavior of LiNi1-zMzO2 (M=Co, Mn, Ti) [J] . J Electrochem Soc, 1997, 144(9): 3 117-3 125.
[18] Nishida Yasunori, Nakane Kenji, Satoh Tomoari. Synthsis and properties of galiium-doped LiNiOz as the cathode materials for lithium secondary batteries [J]. J Power Sources, 1997, 68:561-568.
[19] Gao Yuan, Yakovleva M V, Ebner W B. Novel LiNi1-xTix/2 Mgx/2O2 compounds as cathode materials for safer lithium-ion battery [J]. Electrochemical and Solid-State Letters, 1998.(1): 117-122.
[20] Delmas C, Menetrial M, Croguennec L, et al. An overview of the Li(Ni, M) O2 syntheses, structures and properties[J] . Electrochim Acta, 1999, 45: 243-253.
[21]Masaki H,Yasuhiko B,Shuji I,et al.Nonaqueous electrolyte lithium secondary battery[P].EP:744 788.(缺专利申请时间).
[22] Woo-Seong Kim, Kwang-il Chung, Yong-Kook Choi, et al. Synthesis and charge-discharge properties of LiNi1-x-yCoxMyO2(M = Al, Ga)compounds[J]. J Power Sources, 2002,5 087:1-9.
[23] Fey G T K, Chen J G, Subramanian V. Electroanalytical and thermal stability studies of multi-doped lithium nickel cobalt oxides[J]. J Power Sources, 2003, 5 375: 1-6.
[24] Fey G T K, Chen J G, Subramanian V. Prepation and electrochemical properties of Zn-doped LiNi0.8Co0.2O2[J] . J Power Sources, 2002, 112: 384-394.
[25] Peter P C, Huang D L, George T K F. Solid-state Li NMR studies of inverse spinel LiNi1-xCoxVO4 cathode materials[J]. J Power Sources, 2000, 90: 95-102.
[26] Hajime A, Masayuki T, Yoji A. Lithium nickelate electrodes with enhanced high-temperature performance and thermal stability[J]. J Power sources, 2000,90: 76-81.
[27] Pouillerie C, Perton F, Biensan Ph, et al. Effect of magnesium substitution on the cycling behavior of lithium nickel cobalt oxide[J]. J Power Sources, 2001, 96: 293-302.
[28] Prado G. Mixed cobalt and iron substituted lithium nickelate: a structural and electrochemical study[J] . Solid State Ionics, 2000, 138: 19-30.
[29] Madhavi S, Subba R G V, Chowdari B V R, et al. Effects of aluminium doping on cathodic behaviour of LiNi0. 7Co0. 3O2 [J]. J Power Sources, 2001, 93: 156-162.
[30] Liu Zhao lin, Yu Aishui, Lee Jim Y. Synthesis and characterization of LiNi1-x-yCoxMnyO2 as the cathode materials of secondary lithium batteries[J] .J Power sources, 1999, 81-82:416-419.
[31] Chowdari B V R, Subba Rao C V. Cathodic behavior of (Co, Ti, Mg) -doped LiNiO2[J] . Solid State Ionics, 2001, 140: 55-62.
基本信息:
中图分类号:TM911
引用信息:
[1]高德淑,苏光耀,肖启振,李文,李朝晖.锂离子电池正极材料LiNiO_2的研究进展[J].电池工业,2004(06):300-304.
2004-12-25
2004-12-25