nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
2026, 04, v.30 447-451
钠离子电池循环过程中膨胀力特性研究
基金项目(Foundation): 海关总署科研项目(项目编号2022HK062)
邮箱(Email): lurq@iqtcnet.cn;
DOI: 10.19996/j.cnki.ChinBatlnd.2026.04.004
发布时间: 2025-12-09
出版时间: 2025-12-09
网络发布时间: 2025-12-09
移动端阅读
摘要:

钠离子电池因资源丰富与成本优势被视为下一代储能技术的核心候选,但其循环过程中因钠离子半径较大引发的体积膨胀效应严重制约了电池的可靠性与寿命。现有研究多聚焦于单一因素(如温度或电压)对膨胀力的影响,对多因素耦合作用下的动态演变机制缺乏探讨。本文通过构建温度(35℃/45℃)与充电截止电压(3.95 V/4.0 V)的多变量协同实验模型,结合原位膨胀力监测分析,揭示了钠离子电池膨胀力的非线性演化规律及其与SEI膜增厚关联机制。研究发现,高温(45℃)与高截止电压(4.0 V)会加剧钠离子嵌入动力学失衡,导致硬碳结构畸变与微孔不可逆填充,并使界面副反应倍增,使电池膨胀力持续增长。此外,提出“膨胀力阈值释放”策略,通过应力释放可将容量保持率短期提升0.5%,为钠离子电池的多维度寿命优化提供理论依据。

Abstract:

Owing to its abundant resources and cost-effectiveness, the sodium-ion battery(SIB) is regarded as a core candidate for next-generation energy storage technologies. However, the relatively large ionic radius of sodium ions induces significant volume expansion during the cycling process, which severely constrains the reliability and lifespan of SIBs. Current research predominantly focuses on the influence of individual factors, such as temperature or voltage, on the expansion force, while the dynamic evolution mechanisms under the coupling of multiple factors remain under explored. In this study, a multi-variable synergistic experimental model incorporating temperature(35 ℃ and 45 ℃) and charging cut-off voltage(3.95 V and 4.0 V) was constructed. Combined with in situ monitoring and analysis of the expansion force, the nonlinear evolution law of the expansion force in SIBs and its correlation mechanism with SEI film thickening were elucidated. It was found that high temperature(45 ℃) and elevated cut-off voltage(4.0 V) exacerbate the kinetic imbalance of sodium ion intercalation, leading to structural distortion and irreversible micropore filling in the hard carbon, thereby triggering a proliferation of interfacial side reactions and a continuous increase in the battery's swelling force. Additionally, a "threshold release of expansion force" strategy was proposed. By releasing stress, the capacity retention rate can be temporarily enhanced by 0.5%, providing a theoretical basis for multidimensional lifespan optimization of sodium-ion batteries.

参考文献

[1]王洪波,向燕宁,孟小吻,等.钠离子电池正极材料NaNi0.4Fe0.2Mn0.4O2的制备与储钠性能[J].电池工业,2024,28(2):66-71.

[2]朱碧玉,王韶华,胡彦玲.钠离子电池正极材料硫酸铁钠专利技术分析[J].电池工业,2024,28(4):206-211,220.

[3]张迈吉,崔国渠,王颢甫,等.低温钠离子电池负极材料研究进展[J].电池工业,2025,29(5):393-405,417.

[4]史永胜,翟欣然,胡玙珺.基于机器学习的钠离子电池剩余使用寿命预测[J].华南师范大学学报(自然科学版),2023,55(3):17-24.

[5]李瑞,何祥飞,郭美卿,等.钠离子电池磷基聚阴离子型正极材料研究进展[J].长沙理工大学学报(自然科学版),2023,20(3):14-31.

[6]闻有为,滕安琪,李勇琦,等.不同放电倍率下钠离子电池的电性能与产热行为研究[J].储能科学与技术,2025,14(4):1687-1697.

[7]袁博,郭进,孔祥辉,等.钠离子电池碳负极材料的研究进展[J].现代工业经济和信息化,2025,15(2):24-26.

[8]陆楠,孙越,彭鹏,等.数据驱动的钠离子电池健康状态评估方法研究[J].电源学报,2024,22(1):1-10.

[9]林春景,李丹华,温浩然,等.动力电池在充电过程中的膨胀力特性[J].储能科学与技术,2022,11(5):1627-1633.

[10]鲁怀敏,方海峰,何向明,等.压力对三元锂电池膨胀及充放电性能的影响[J].电源技术,2017,41(5):686-688.

[11]Michelini E,Höschele P,Heindl S F,et al.Experimental investigation on reversible swelling mechanisms of lithium-ion batteries under a varying preload force[J].Batteries,2023,9(4):218.

[12]吉顺,王金林,郭雨洁,等.硬碳储钠负极材料研究进展[J].矿冶,2024,33(5):757-765.

[13]董瑞琪,吴锋,白莹,等.钠离子电池硬碳负极储钠机理及优化策略[J].化学学报,2021,79(12):1461-1476.

[14]曹文栋,周丹.钠离子电池层状氧化物正极材料的掺杂改性策略研究进展[J/OL].硅酸盐学报,2025:1-35.[2026-02-08]. https://link. cnki. net/doi/10.14062/j.issn.0454-5648.20250079.

基本信息:

DOI:10.19996/j.cnki.ChinBatlnd.2026.04.004

中图分类号:TM912

引用信息:

[1]程文彬,莫梁君,林嘉铭,等.钠离子电池循环过程中膨胀力特性研究[J].电池工业,2026,30(04):447-451.DOI:10.19996/j.cnki.ChinBatlnd.2026.04.004.

基金信息:

海关总署科研项目(项目编号2022HK062)

发布时间:

2025-12-09

出版时间:

2025-12-09

网络发布时间:

2025-12-09

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文