| 1,003 | 10 | 130 |
| 下载次数 | 被引频次 | 阅读次数 |
直接甲醇燃料电池(DMFC)功率密度高,燃料甲醇易得、储存和携带方便,既可作为大型的动力电源,又可作为小型电子设备的电源,是目前燃料电池研究领域的一个热点。但由于甲醇渗透、贵金属的使用等问题,阴极催化剂还有很多方面需要改善。介绍了近年来直接甲醇燃料电池阴极催化剂的研究与进展,提出了存在的问题及可能的发展趋势。
Abstract：Direct methanol fuel cell(DMFC) has many advantages,such as high power density,abundant sources for methanol,convenience in storage and transportation of methanol.It can be used not only as the power for electric vehicle in large scale but also as the power for small electrical equipments,so that it has attracted much attention.However,because there are a lot of problems that affect the catalytic activity of the cathode,such as the methanol crossover and the use of noble metal,cathode catalysts for DMFC need to be improved.The recent research and development on cathode catalysts for DMFC are introduced and the problem,the possible trend are proposed in this paper.
[1]李旭光,邢巍,唐亚文,等.直接甲醇燃料电池阴极电催化剂的研究进展[J].化学通报,2003,(8):521-527.
[2]Baranton S,Coutanceau C,Roux C,et al.Oxygen reductionreaction in acid medium at iron phthalocyanine dispersed onhigh surface area carbon substrate:tolerance to methanol,stability and kinetics[J].Journal of Electroanalytical Chem-istry,2005,577:223-234.
[3]李旭光,邢魏,陆天虹,等.直接甲醇燃料电池的耐甲醇阴极电催化剂炭载四羧基酞菁钴的研究[J].高等学校化学学报,2003,24(7):1246-1250.
[4]黄庆红,唐亚文,马振旄,等.直接甲醇燃料电池阴极催化剂的研究进展[J].应用化学,2005,22(12):1277-1281.
[5]Koji Makino,Kazuyoshi Furukawa,Keiichi Okajima eatl.Per-formance of sputter-deposited platinum cathodes with Nafionand carbon loading for direct methanol fuel cells[J].J PowerSources,2007,166:30-34.
[6]Yang Hui,Nicolas Alonso-Vante,Claude Lamy,et al.Highmethanol tolerance of carbon-supported Pt-Cr alloy nanopar-ticle electrocatalysts for oxygen reduction[J].Journal of TheElectrochemical Society,2005,152(4):A704-A709.
[7]韩飞,刘长鹏,邢巍,等.直接甲醇燃料电池的研究进展[J].应Vol.13 No.2 Apr.2008用化学,2004,21(9):865-871.
[8]Su'arez-Alc'antara K,Rodr'y'guez-Castellanos,Dante A R,et al.RuxCrySez electrocatalyst for oxygen reduction in a poly-mer electrolyte membrane fuel cell[J].J Power Sources,2006(157):114-120.
[9]Drillet J-F,Ee A,Friedemann J,et al.Oxygen reduction atPt and Pt70Ni30 in H2SO4/CH3OH solution[J].ElectrochimicalActa,2002,47:1983-1988.
[10]黄幼菊,李伟善,黄青丹,等.氢钼青铜对铂催化氧还原反应的促进作用[J].高等学校化学学报,2007,28(5):921-924.
[11]韩飞,李旭光,邢巍,等.耐甲醇氧还原复合催化剂四苯基铁卟啉-铂的研究[J].应用化学,2003,20(5):458-461.
[12]Chu Deryn,Jiang Rongzhong.Novel electrocatalysts for di-rect methanol fuel cells[J].Solid State Ionics,2002(148):591-599.
[13]刘淑清,徐吉庆,孙浩然,等.卟啉.金属氧簇超分子化合物的光谱及电催化氧还原[J].物理化学学报,2001,17(2):128-133.
[14]Lu Yuhao,Ramana G Reddy.The electrochemical behaviorof cobalt phthalocyanine/platinum as methanol-resistantoxygen-reduction electrocatalysts for DMFC[J].Elec-trochimica Acta,2007(52):2562-2569.
[15]张红芬,潘景浩.卟啉及金属卟啉的应用[J].化学教育,2005,(4):3-8.
[16]Jae Kwang Lee,Jinsub Choi,Sung Jin Kang,et al.Influenceof copper oxide modification of a platinum cathode on theactivity of direct methanol fuel cell[J].Electrochimica Acta,2007,52(6):2272-2276.
[17]苏怡,刘长鹏,单义斌,等.磷钼酸对直接甲醇燃料电池阴极氧还原的促进作用[J].高等学校化学学报,2005,26(6):1114-1117.
[18]高峰,钟顺和.CaF2负载H3Pmo12O40表面上激光促进甲烷部分氧化反应性能的研究[J].高等学校化学学报,2001,22(5):833-835.
基本信息:
中图分类号:TM911.4
引用信息:
[1]郭盼盼,李伟善,黄幼菊.直接甲醇燃料电池阴极催化剂的研究进展[J].电池工业,2008,No.74(02):141-144.
2008-04-25
2008-04-25